Crystal structure of catena-poly[diammonium [di-μ-oxalato-cuprate(II)]]

The structure of the title compound, {(NH4)2[Cu(C2O4)2]}n, at 100 K has monoclinic (P21/c) symmetry with the CuII atom on an inversion center. The compound has a polymeric structure due to long Cu...O interactions which create [Cu(C2O4)2] chains along the a axis. The structure also displays intermol...

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Main Authors: Diane A. Dickie, Richard A. Kemp
Format: Article
Language:English
Published: International Union of Crystallography 2016-12-01
Series:Acta Crystallographica Section E: Crystallographic Communications
Subjects:
Online Access:http://scripts.iucr.org/cgi-bin/paper?S2056989016017631
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spelling doaj-e858c6d6a3f140d09d9c1e24085950f92020-11-25T01:57:41ZengInternational Union of CrystallographyActa Crystallographica Section E: Crystallographic Communications2056-98902016-12-0172121780178210.1107/S2056989016017631pj2038Crystal structure of catena-poly[diammonium [di-μ-oxalato-cuprate(II)]]Diane A. Dickie0Richard A. Kemp1Department of Chemistry and Chemical Biology, MSC03 2060, 1 University of New Mexico, Albuquerque, NM 87131, USADepartment of Chemistry and Chemical Biology, MSC03 2060, 1 University of New Mexico, Albuquerque, NM 87131, USAThe structure of the title compound, {(NH4)2[Cu(C2O4)2]}n, at 100 K has monoclinic (P21/c) symmetry with the CuII atom on an inversion center. The compound has a polymeric structure due to long Cu...O interactions which create [Cu(C2O4)2] chains along the a axis. The structure also displays intermolecular N—H...O hydrogen bonding, which links these chains into a three-dimensional network.http://scripts.iucr.org/cgi-bin/paper?S2056989016017631crystal structurecopperoxalatehydrogen bondingammonium
collection DOAJ
language English
format Article
sources DOAJ
author Diane A. Dickie
Richard A. Kemp
spellingShingle Diane A. Dickie
Richard A. Kemp
Crystal structure of catena-poly[diammonium [di-μ-oxalato-cuprate(II)]]
Acta Crystallographica Section E: Crystallographic Communications
crystal structure
copper
oxalate
hydrogen bonding
ammonium
author_facet Diane A. Dickie
Richard A. Kemp
author_sort Diane A. Dickie
title Crystal structure of catena-poly[diammonium [di-μ-oxalato-cuprate(II)]]
title_short Crystal structure of catena-poly[diammonium [di-μ-oxalato-cuprate(II)]]
title_full Crystal structure of catena-poly[diammonium [di-μ-oxalato-cuprate(II)]]
title_fullStr Crystal structure of catena-poly[diammonium [di-μ-oxalato-cuprate(II)]]
title_full_unstemmed Crystal structure of catena-poly[diammonium [di-μ-oxalato-cuprate(II)]]
title_sort crystal structure of catena-poly[diammonium [di-μ-oxalato-cuprate(ii)]]
publisher International Union of Crystallography
series Acta Crystallographica Section E: Crystallographic Communications
issn 2056-9890
publishDate 2016-12-01
description The structure of the title compound, {(NH4)2[Cu(C2O4)2]}n, at 100 K has monoclinic (P21/c) symmetry with the CuII atom on an inversion center. The compound has a polymeric structure due to long Cu...O interactions which create [Cu(C2O4)2] chains along the a axis. The structure also displays intermolecular N—H...O hydrogen bonding, which links these chains into a three-dimensional network.
topic crystal structure
copper
oxalate
hydrogen bonding
ammonium
url http://scripts.iucr.org/cgi-bin/paper?S2056989016017631
work_keys_str_mv AT dianeadickie crystalstructureofcatenapolydiammoniumdimoxalatocuprateii
AT richardakemp crystalstructureofcatenapolydiammoniumdimoxalatocuprateii
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