Crystal structure of catena-poly[diammonium [di-μ-oxalato-cuprate(II)]]
The structure of the title compound, {(NH4)2[Cu(C2O4)2]}n, at 100 K has monoclinic (P21/c) symmetry with the CuII atom on an inversion center. The compound has a polymeric structure due to long Cu...O interactions which create [Cu(C2O4)2] chains along the a axis. The structure also displays intermol...
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International Union of Crystallography
2016-12-01
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Online Access: | http://scripts.iucr.org/cgi-bin/paper?S2056989016017631 |
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doaj-e858c6d6a3f140d09d9c1e24085950f92020-11-25T01:57:41ZengInternational Union of CrystallographyActa Crystallographica Section E: Crystallographic Communications2056-98902016-12-0172121780178210.1107/S2056989016017631pj2038Crystal structure of catena-poly[diammonium [di-μ-oxalato-cuprate(II)]]Diane A. Dickie0Richard A. Kemp1Department of Chemistry and Chemical Biology, MSC03 2060, 1 University of New Mexico, Albuquerque, NM 87131, USADepartment of Chemistry and Chemical Biology, MSC03 2060, 1 University of New Mexico, Albuquerque, NM 87131, USAThe structure of the title compound, {(NH4)2[Cu(C2O4)2]}n, at 100 K has monoclinic (P21/c) symmetry with the CuII atom on an inversion center. The compound has a polymeric structure due to long Cu...O interactions which create [Cu(C2O4)2] chains along the a axis. The structure also displays intermolecular N—H...O hydrogen bonding, which links these chains into a three-dimensional network.http://scripts.iucr.org/cgi-bin/paper?S2056989016017631crystal structurecopperoxalatehydrogen bondingammonium |
collection |
DOAJ |
language |
English |
format |
Article |
sources |
DOAJ |
author |
Diane A. Dickie Richard A. Kemp |
spellingShingle |
Diane A. Dickie Richard A. Kemp Crystal structure of catena-poly[diammonium [di-μ-oxalato-cuprate(II)]] Acta Crystallographica Section E: Crystallographic Communications crystal structure copper oxalate hydrogen bonding ammonium |
author_facet |
Diane A. Dickie Richard A. Kemp |
author_sort |
Diane A. Dickie |
title |
Crystal structure of catena-poly[diammonium [di-μ-oxalato-cuprate(II)]] |
title_short |
Crystal structure of catena-poly[diammonium [di-μ-oxalato-cuprate(II)]] |
title_full |
Crystal structure of catena-poly[diammonium [di-μ-oxalato-cuprate(II)]] |
title_fullStr |
Crystal structure of catena-poly[diammonium [di-μ-oxalato-cuprate(II)]] |
title_full_unstemmed |
Crystal structure of catena-poly[diammonium [di-μ-oxalato-cuprate(II)]] |
title_sort |
crystal structure of catena-poly[diammonium [di-μ-oxalato-cuprate(ii)]] |
publisher |
International Union of Crystallography |
series |
Acta Crystallographica Section E: Crystallographic Communications |
issn |
2056-9890 |
publishDate |
2016-12-01 |
description |
The structure of the title compound, {(NH4)2[Cu(C2O4)2]}n, at 100 K has monoclinic (P21/c) symmetry with the CuII atom on an inversion center. The compound has a polymeric structure due to long Cu...O interactions which create [Cu(C2O4)2] chains along the a axis. The structure also displays intermolecular N—H...O hydrogen bonding, which links these chains into a three-dimensional network. |
topic |
crystal structure copper oxalate hydrogen bonding ammonium |
url |
http://scripts.iucr.org/cgi-bin/paper?S2056989016017631 |
work_keys_str_mv |
AT dianeadickie crystalstructureofcatenapolydiammoniumdimoxalatocuprateii AT richardakemp crystalstructureofcatenapolydiammoniumdimoxalatocuprateii |
_version_ |
1724973267478904832 |