Crystal structure of N,N,N-tris[(1,3-benzothiazol-2-yl)methyl]amine
The title compound, C24H18N4S3, exhibits three near planar benzothiazole systems in a pseudo-C3 conformation. The dihedral angles between the planes of the benzothiazole groups range from 112.56 (4) to 124.68 (4)° In the crystal, molecules are connected to each other through three short C—H...N cont...
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International Union of Crystallography
2015-10-01
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| Series: | Acta Crystallographica Section E: Crystallographic Communications |
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| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S2056989015017417 |
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doaj-e8376878449b499b94f30d0835fe51262020-11-24T23:38:02ZengInternational Union of CrystallographyActa Crystallographica Section E: Crystallographic Communications2056-98902015-10-017110o786o78710.1107/S2056989015017417ff2141Crystal structure of N,N,N-tris[(1,3-benzothiazol-2-yl)methyl]amineVelabo Mdluli0James A. Golen1Arnold L. Rheingold2David R. Manke3Department of Chemistry and Biochemistry, University of Massachusetts Dartmouth, 285 Old Westport Road, North Dartmouth, MA 02747, USADepartment of Chemistry, University of California, San Diego, 9500 Gilman Drive, La Jolla, CA 92093, USADepartment of Chemistry, University of California, San Diego, 9500 Gilman Drive, La Jolla, CA 92093, USADepartment of Chemistry and Biochemistry, University of Massachusetts Dartmouth, 285 Old Westport Road, North Dartmouth, MA 02747, USAThe title compound, C24H18N4S3, exhibits three near planar benzothiazole systems in a pseudo-C3 conformation. The dihedral angles between the planes of the benzothiazole groups range from 112.56 (4) to 124.68 (4)° In the crystal, molecules are connected to each other through three short C—H...N contacts, forming an infinite chain along [100]. The molecules are also linked by π–π interactions with each of the three five-membered thiazole rings. [inter-centroid distance range: 3.614 (1)–4.074 (1) Å, inter-planar distance range: 3.4806 (17)–3.6902 (15) Å, slippage range: 0.759 (3)–1.887 (3) Å].http://scripts.iucr.org/cgi-bin/paper?S2056989015017417crystal structurebenzothiazolesC—H...N interactions |
| collection |
DOAJ |
| language |
English |
| format |
Article |
| sources |
DOAJ |
| author |
Velabo Mdluli James A. Golen Arnold L. Rheingold David R. Manke |
| spellingShingle |
Velabo Mdluli James A. Golen Arnold L. Rheingold David R. Manke Crystal structure of N,N,N-tris[(1,3-benzothiazol-2-yl)methyl]amine Acta Crystallographica Section E: Crystallographic Communications crystal structure benzothiazoles C—H...N interactions |
| author_facet |
Velabo Mdluli James A. Golen Arnold L. Rheingold David R. Manke |
| author_sort |
Velabo Mdluli |
| title |
Crystal structure of N,N,N-tris[(1,3-benzothiazol-2-yl)methyl]amine |
| title_short |
Crystal structure of N,N,N-tris[(1,3-benzothiazol-2-yl)methyl]amine |
| title_full |
Crystal structure of N,N,N-tris[(1,3-benzothiazol-2-yl)methyl]amine |
| title_fullStr |
Crystal structure of N,N,N-tris[(1,3-benzothiazol-2-yl)methyl]amine |
| title_full_unstemmed |
Crystal structure of N,N,N-tris[(1,3-benzothiazol-2-yl)methyl]amine |
| title_sort |
crystal structure of n,n,n-tris[(1,3-benzothiazol-2-yl)methyl]amine |
| publisher |
International Union of Crystallography |
| series |
Acta Crystallographica Section E: Crystallographic Communications |
| issn |
2056-9890 |
| publishDate |
2015-10-01 |
| description |
The title compound, C24H18N4S3, exhibits three near planar benzothiazole systems in a pseudo-C3 conformation. The dihedral angles between the planes of the benzothiazole groups range from 112.56 (4) to 124.68 (4)° In the crystal, molecules are connected to each other through three short C—H...N contacts, forming an infinite chain along [100]. The molecules are also linked by π–π interactions with each of the three five-membered thiazole rings. [inter-centroid distance range: 3.614 (1)–4.074 (1) Å, inter-planar distance range: 3.4806 (17)–3.6902 (15) Å, slippage range: 0.759 (3)–1.887 (3) Å]. |
| topic |
crystal structure benzothiazoles C—H...N interactions |
| url |
http://scripts.iucr.org/cgi-bin/paper?S2056989015017417 |
| work_keys_str_mv |
AT velabomdluli crystalstructureofnnntris13benzothiazol2ylmethylamine AT jamesagolen crystalstructureofnnntris13benzothiazol2ylmethylamine AT arnoldlrheingold crystalstructureofnnntris13benzothiazol2ylmethylamine AT davidrmanke crystalstructureofnnntris13benzothiazol2ylmethylamine |
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1725518013205053440 |