EFFECTS OF MAGHNITE NANOCLAY MODIFICATION AND COMPATIBILIZATION ON THE PHYSICAL AND MORPHOLOGICAL PROPERTIES OF POLY(VINYL CHLORIDE)/POLY(ETHYLENE-CO-VINYL ACETATE) BLENDS
In this research work poly(vinyl chloride)(PVC), ethylene vinyl acetate copolymer (EVA), and Maghnite nanoclay (MGT) were used to prepare PVC/EVA nanocomposites. The MGT clay was intercalated with octadecyltrimethylammonium chloride (ODTMA) and grafted with γ-aminopropyltriethoxysil...
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doaj-e812e99f29e14ae2b24451e68130d2902020-11-24T22:23:03ZengEl Oued UniversityJournal of Fundamental and Applied Sciences2588-19141112-98672018-12-0111110.4314/jfas.v11i1.22150EFFECTS OF MAGHNITE NANOCLAY MODIFICATION AND COMPATIBILIZATION ON THE PHYSICAL AND MORPHOLOGICAL PROPERTIES OF POLY(VINYL CHLORIDE)/POLY(ETHYLENE-CO-VINYL ACETATE) BLENDSI. Bouaziz0R. Doufnoune1N. Haddaoui2D. Benachour3F. J. Baltä-Calleja4URMES, Equipe de Valorisation des Polymères, Université Ferhat ABBAS Sétif-1, AlgérieDépartement de Génie des Procédés, Faculté de Technologie, Université Ferhat ABBAS Sétif-1, AlgérieLaboratoire LPCHP, Faculté de Technologie, Université Ferhat ABBAS Sétif-1, AlgérieLaboratoire LMPMP, Faculté de Technologie, Université Ferhat ABBAS Sétif-1, AlgérieInstituto de Estructura de la Materia, CSIC, Serrano 119, 28006 Madrid, Spain In this research work poly(vinyl chloride)(PVC), ethylene vinyl acetate copolymer (EVA), and Maghnite nanoclay (MGT) were used to prepare PVC/EVA nanocomposites. The MGT clay was intercalated with octadecyltrimethylammonium chloride (ODTMA) and grafted with γ-aminopropyltriethoxysilane (APTES). The blend nanocomposites were prepared through the melt mixing of PVC/EVA blend at a weight ratio of 50/50 (wt%/wt%) with 20 wt% of compatibilizer; ethylene vinyl acetate grafted with an alcohol (EVA-g-OH) and 3 wt% of modified MGT clay using a Brabender plastograph. The nanocomposites so prepared were characterized using X-ray diffraction, TGA/DTA, mechanical tests and SEM. The results showed that when PVC was blended with EVA, with the modified MGT and with the compatibilizer, synergistic effects in the thermal stability and mechanical properties were observed. http://www.jfas.info/index.php/JFAS/article/view/150Nanocomposites; PVC; EVA; Maghnite nanoclay; Modification; Compatibilizer. |
collection |
DOAJ |
language |
English |
format |
Article |
sources |
DOAJ |
author |
I. Bouaziz R. Doufnoune N. Haddaoui D. Benachour F. J. Baltä-Calleja |
spellingShingle |
I. Bouaziz R. Doufnoune N. Haddaoui D. Benachour F. J. Baltä-Calleja EFFECTS OF MAGHNITE NANOCLAY MODIFICATION AND COMPATIBILIZATION ON THE PHYSICAL AND MORPHOLOGICAL PROPERTIES OF POLY(VINYL CHLORIDE)/POLY(ETHYLENE-CO-VINYL ACETATE) BLENDS Journal of Fundamental and Applied Sciences Nanocomposites; PVC; EVA; Maghnite nanoclay; Modification; Compatibilizer. |
author_facet |
I. Bouaziz R. Doufnoune N. Haddaoui D. Benachour F. J. Baltä-Calleja |
author_sort |
I. Bouaziz |
title |
EFFECTS OF MAGHNITE NANOCLAY MODIFICATION AND COMPATIBILIZATION ON THE PHYSICAL AND MORPHOLOGICAL PROPERTIES OF POLY(VINYL CHLORIDE)/POLY(ETHYLENE-CO-VINYL ACETATE) BLENDS |
title_short |
EFFECTS OF MAGHNITE NANOCLAY MODIFICATION AND COMPATIBILIZATION ON THE PHYSICAL AND MORPHOLOGICAL PROPERTIES OF POLY(VINYL CHLORIDE)/POLY(ETHYLENE-CO-VINYL ACETATE) BLENDS |
title_full |
EFFECTS OF MAGHNITE NANOCLAY MODIFICATION AND COMPATIBILIZATION ON THE PHYSICAL AND MORPHOLOGICAL PROPERTIES OF POLY(VINYL CHLORIDE)/POLY(ETHYLENE-CO-VINYL ACETATE) BLENDS |
title_fullStr |
EFFECTS OF MAGHNITE NANOCLAY MODIFICATION AND COMPATIBILIZATION ON THE PHYSICAL AND MORPHOLOGICAL PROPERTIES OF POLY(VINYL CHLORIDE)/POLY(ETHYLENE-CO-VINYL ACETATE) BLENDS |
title_full_unstemmed |
EFFECTS OF MAGHNITE NANOCLAY MODIFICATION AND COMPATIBILIZATION ON THE PHYSICAL AND MORPHOLOGICAL PROPERTIES OF POLY(VINYL CHLORIDE)/POLY(ETHYLENE-CO-VINYL ACETATE) BLENDS |
title_sort |
effects of maghnite nanoclay modification and compatibilization on the physical and morphological properties of poly(vinyl chloride)/poly(ethylene-co-vinyl acetate) blends |
publisher |
El Oued University |
series |
Journal of Fundamental and Applied Sciences |
issn |
2588-1914 1112-9867 |
publishDate |
2018-12-01 |
description |
In this research work poly(vinyl chloride)(PVC), ethylene vinyl acetate copolymer (EVA), and Maghnite nanoclay (MGT) were used to prepare PVC/EVA nanocomposites. The MGT clay was intercalated with octadecyltrimethylammonium chloride (ODTMA) and grafted with γ-aminopropyltriethoxysilane (APTES). The blend nanocomposites were prepared through the melt mixing of PVC/EVA blend at a weight ratio of 50/50 (wt%/wt%) with 20 wt% of compatibilizer; ethylene vinyl acetate grafted with an alcohol (EVA-g-OH) and 3 wt% of modified MGT clay using a Brabender plastograph. The nanocomposites so prepared were characterized using X-ray diffraction, TGA/DTA, mechanical tests and SEM. The results showed that when PVC was blended with EVA, with the modified MGT and with the compatibilizer, synergistic effects in the thermal stability and mechanical properties were observed.
|
topic |
Nanocomposites; PVC; EVA; Maghnite nanoclay; Modification; Compatibilizer. |
url |
http://www.jfas.info/index.php/JFAS/article/view/150 |
work_keys_str_mv |
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