Bis[1-(2-hydroxyethyl)-2-methyl-5-nitro-1H-imidazole-κN3]silver(I) nitrate

In the title compound, [Ag(C6H9N3O3)2]NO3, the Ag atom is bicoordinated in a distorted linear configuration by two 1-(2-hydroxyethyl)-2-methyl-5-nitroimidazole ligands through one of the N atoms. The dihedral angle between the two imidazole rings is 16.1 (2)°. The O atoms of the n...

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Main Authors: T. Balasubramanian, Samuel Robinson Jebas, Hoong-Kun Fun
Format: Article
Language:English
Published: International Union of Crystallography 2008-05-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S1600536808009860
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spelling doaj-e775dc64dfe44dd4ad82ba3cbef148862020-11-24T21:50:24ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682008-05-01645m668m66910.1107/S1600536808009860Bis[1-(2-hydroxyethyl)-2-methyl-5-nitro-1H-imidazole-κN3]silver(I) nitrateT. BalasubramanianSamuel Robinson JebasHoong-Kun FunIn the title compound, [Ag(C6H9N3O3)2]NO3, the Ag atom is bicoordinated in a distorted linear configuration by two 1-(2-hydroxyethyl)-2-methyl-5-nitroimidazole ligands through one of the N atoms. The dihedral angle between the two imidazole rings is 16.1 (2)°. The O atoms of the nitrate anion are disordered over two positions; the site occupancy factors are 0.8 and 0.2. The ions are connected by C—H...O interactions, while two weak intramolecular C—H...O interactions producing an S(6) ring motif are observed. The nitrate anion is linked to the hydroxyl groups of two neighbouring cations by O—H...O hydrogen bonds. The ions are packed into infinite chains along the [100] direction.http://scripts.iucr.org/cgi-bin/paper?S1600536808009860
collection DOAJ
language English
format Article
sources DOAJ
author T. Balasubramanian
Samuel Robinson Jebas
Hoong-Kun Fun
spellingShingle T. Balasubramanian
Samuel Robinson Jebas
Hoong-Kun Fun
Bis[1-(2-hydroxyethyl)-2-methyl-5-nitro-1H-imidazole-κN3]silver(I) nitrate
Acta Crystallographica Section E
author_facet T. Balasubramanian
Samuel Robinson Jebas
Hoong-Kun Fun
author_sort T. Balasubramanian
title Bis[1-(2-hydroxyethyl)-2-methyl-5-nitro-1H-imidazole-κN3]silver(I) nitrate
title_short Bis[1-(2-hydroxyethyl)-2-methyl-5-nitro-1H-imidazole-κN3]silver(I) nitrate
title_full Bis[1-(2-hydroxyethyl)-2-methyl-5-nitro-1H-imidazole-κN3]silver(I) nitrate
title_fullStr Bis[1-(2-hydroxyethyl)-2-methyl-5-nitro-1H-imidazole-κN3]silver(I) nitrate
title_full_unstemmed Bis[1-(2-hydroxyethyl)-2-methyl-5-nitro-1H-imidazole-κN3]silver(I) nitrate
title_sort bis[1-(2-hydroxyethyl)-2-methyl-5-nitro-1h-imidazole-κn3]silver(i) nitrate
publisher International Union of Crystallography
series Acta Crystallographica Section E
issn 1600-5368
publishDate 2008-05-01
description In the title compound, [Ag(C6H9N3O3)2]NO3, the Ag atom is bicoordinated in a distorted linear configuration by two 1-(2-hydroxyethyl)-2-methyl-5-nitroimidazole ligands through one of the N atoms. The dihedral angle between the two imidazole rings is 16.1 (2)°. The O atoms of the nitrate anion are disordered over two positions; the site occupancy factors are 0.8 and 0.2. The ions are connected by C—H...O interactions, while two weak intramolecular C—H...O interactions producing an S(6) ring motif are observed. The nitrate anion is linked to the hydroxyl groups of two neighbouring cations by O—H...O hydrogen bonds. The ions are packed into infinite chains along the [100] direction.
url http://scripts.iucr.org/cgi-bin/paper?S1600536808009860
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AT samuelrobinsonjebas bis12hydroxyethyl2methyl5nitro1himidazole954n3silverinitrate
AT hoongkunfun bis12hydroxyethyl2methyl5nitro1himidazole954n3silverinitrate
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