The study of partial and excess molar volumes for binary mixtures of nitrobenzene and benzaldehyde with xylene isomers from T = (298.15 to 318.15) K and P = 0.087 MPa

• Main Authors: Hamid R. Rafiee, Farshid Frouzesh
• Format: Article
• Language: English
• Published: Elsevier 2016-09-01
• Series: Journal of Advanced Research
• Subjects: Density; Redlich–Kister; Volumetric; Excess molar volume; Xylenes
• Online Access: http://www.sciencedirect.com/science/article/pii/S2090123215001113

Based on density measurements, partial and excess molar volumes for binary mixtures of nitrobenzene and benzaldehyde with three isomers of xylene have been measured. The whole range of composition and temperatures from T = (298.15 to 318.15) K at ambient pressure 0.087 MPa, has been considered. The excess molar volumes were negative and decreased by increasing temperature for all mixtures which are explained based on intermolecular interactions. Excess molar volumes for solutions including nitrobenzene were absolutely larger than benzaldehyde binary mixtures. The partial and excess molar volumes for each component have been appraised and reported. The excess molar volumes have been successfully fitted to Redlich–Kister equation.