Thermodynamic description of phase equilibrium in systems MCl5–M’Cl5, (M = Nb, Ta, Mo, W, Re) and MCl3–M’Cl3, (M = Ln)

The paper considers the Saint-John-Bloch model and proves that this model is applicable for describing phase equilibrium in binary systems formed by pentachlorides of d-elements of groups V, Vl, Vll of the periodic system and lanthanide chlorides. The dependence of the possibility of forming solid s...

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Main Authors:	A. V. Galantsev, D. V. Drobot, L. V. Yanshina
Format:	Article
Language:	Russian
Published:	MIREA - Russian Technological University 2011-02-01
Series:	Тонкие химические технологии
Subjects:	saint-john-bloch diagram binary systems phase equilibrium lanthanides
Online Access:	https://www.finechem-mirea.ru/jour/article/view/886

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spelling	doaj-e6517834bfd44941bd68a17716aa60b92021-07-28T13:23:54ZrusMIREA - Russian Technological UniversityТонкие химические технологии2410-65932686-75752011-02-01617981880Thermodynamic description of phase equilibrium in systems MCl<sub>5</sub>–M<sup>’</sup>Cl<sub>5</sub>, (M = Nb, Ta, Mo, W, Re) and MCl<sub>3</sub>–M<sup>’</sup>Cl<sub>3</sub>, (M = Ln)A. V. Galantsev0D. V. Drobot1L. V. Yanshina2M.V. Lomonosov Moscow State University of Fine Chemical Technologies, 86, Vernadskogo pr., Moscow 119571M.V. Lomonosov Moscow State University of Fine Chemical Technologies, 86, Vernadskogo pr., Moscow 119571МГУ им. М.В. ЛомоносоваThe paper considers the Saint-John-Bloch model and proves that this model is applicable for describing phase equilibrium in binary systems formed by pentachlorides of d-elements of groups V, Vl, Vll of the periodic system and lanthanide chlorides. The dependence of the possibility of forming solid solutions in LnCl3-Ln'Cl3 on the atomic number of a lanthanide was found.https://www.finechem-mirea.ru/jour/article/view/886saint-john-bloch diagrambinary systemsphase equilibriumlanthanides
collection	DOAJ
language	Russian
format	Article
sources	DOAJ
author	A. V. Galantsev D. V. Drobot L. V. Yanshina
spellingShingle	A. V. Galantsev D. V. Drobot L. V. Yanshina Thermodynamic description of phase equilibrium in systems MCl<sub>5</sub>–M<sup>’</sup>Cl<sub>5</sub>, (M = Nb, Ta, Mo, W, Re) and MCl<sub>3</sub>–M<sup>’</sup>Cl<sub>3</sub>, (M = Ln) Тонкие химические технологии saint-john-bloch diagram binary systems phase equilibrium lanthanides
author_facet	A. V. Galantsev D. V. Drobot L. V. Yanshina
author_sort	A. V. Galantsev
title	Thermodynamic description of phase equilibrium in systems MCl<sub>5</sub>–M<sup>’</sup>Cl<sub>5</sub>, (M = Nb, Ta, Mo, W, Re) and MCl<sub>3</sub>–M<sup>’</sup>Cl<sub>3</sub>, (M = Ln)
title_short	Thermodynamic description of phase equilibrium in systems MCl<sub>5</sub>–M<sup>’</sup>Cl<sub>5</sub>, (M = Nb, Ta, Mo, W, Re) and MCl<sub>3</sub>–M<sup>’</sup>Cl<sub>3</sub>, (M = Ln)
title_full	Thermodynamic description of phase equilibrium in systems MCl<sub>5</sub>–M<sup>’</sup>Cl<sub>5</sub>, (M = Nb, Ta, Mo, W, Re) and MCl<sub>3</sub>–M<sup>’</sup>Cl<sub>3</sub>, (M = Ln)
title_fullStr	Thermodynamic description of phase equilibrium in systems MCl<sub>5</sub>–M<sup>’</sup>Cl<sub>5</sub>, (M = Nb, Ta, Mo, W, Re) and MCl<sub>3</sub>–M<sup>’</sup>Cl<sub>3</sub>, (M = Ln)
title_full_unstemmed	Thermodynamic description of phase equilibrium in systems MCl<sub>5</sub>–M<sup>’</sup>Cl<sub>5</sub>, (M = Nb, Ta, Mo, W, Re) and MCl<sub>3</sub>–M<sup>’</sup>Cl<sub>3</sub>, (M = Ln)
title_sort	thermodynamic description of phase equilibrium in systems mcl<sub>5</sub>–m<sup>’</sup>cl<sub>5</sub>, (m = nb, ta, mo, w, re) and mcl<sub>3</sub>–m<sup>’</sup>cl<sub>3</sub>, (m = ln)
publisher	MIREA - Russian Technological University
series	Тонкие химические технологии
issn	2410-6593 2686-7575
publishDate	2011-02-01
description	The paper considers the Saint-John-Bloch model and proves that this model is applicable for describing phase equilibrium in binary systems formed by pentachlorides of d-elements of groups V, Vl, Vll of the periodic system and lanthanide chlorides. The dependence of the possibility of forming solid solutions in LnCl3-Ln'Cl3 on the atomic number of a lanthanide was found.
topic	saint-john-bloch diagram binary systems phase equilibrium lanthanides
url	https://www.finechem-mirea.ru/jour/article/view/886
work_keys_str_mv	AT avgalantsev thermodynamicdescriptionofphaseequilibriuminsystemsmclsub5submsupsupclsub5submnbtamowreandmclsub3submsupsupclsub3submln AT dvdrobot thermodynamicdescriptionofphaseequilibriuminsystemsmclsub5submsupsupclsub5submnbtamowreandmclsub3submsupsupclsub3submln AT lvyanshina thermodynamicdescriptionofphaseequilibriuminsystemsmclsub5submsupsupclsub5submnbtamowreandmclsub3submsupsupclsub3submln
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Thermodynamic description of phase equilibrium in systems MCl<sub>5</sub>–M<sup>’</sup>Cl<sub>5</sub>, (M = Nb, Ta, Mo, W, Re) and MCl<sub>3</sub>–M<sup>’</sup>Cl<sub>3</sub>, (M = Ln)

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