Thermodynamic description of phase equilibrium in systems MCl<sub>5</sub>–M<sup>’</sup>Cl<sub>5</sub>, (M = Nb, Ta, Mo, W, Re) and MCl<sub>3</sub>–M<sup>’</sup>Cl<sub>3</sub>, (M = Ln)
The paper considers the Saint-John-Bloch model and proves that this model is applicable for describing phase equilibrium in binary systems formed by pentachlorides of d-elements of groups V, Vl, Vll of the periodic system and lanthanide chlorides. The dependence of the possibility of forming solid s...
Main Authors: | , , |
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Format: | Article |
Language: | Russian |
Published: |
MIREA - Russian Technological University
2011-02-01
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Series: | Тонкие химические технологии |
Subjects: | |
Online Access: | https://www.finechem-mirea.ru/jour/article/view/886 |