Synthesis and Supramolecular Structure of a (5-(3-(1H-tetrazol-5-yl)phenyl)-1H-tetrazole) Cobalt Complex

The reaction of CoCl2·6H2O with m-BDTH2 (1,3-benzeneditetrazol-5-yl) leads to [Co(C8H6N8)2(H2O)2(CH3CN)2]Cl2 (1). Both tetrazolic groups remain protonated existing in a 1H tautomeric form. A trifurcated chlorine atom and stacking interactions assemble compound 1 into a three-dimensional network.

Bibliographic Details
Main Authors:	George E. Kostakis, Christopher E. Anson, Annie K. Powell
Format:	Article
Language:	English
Published:	Hindawi Limited 2010-01-01
Series:	Bioinorganic Chemistry and Applications
Online Access:	http://dx.doi.org/10.1155/2010/104329

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spelling	doaj-e6502e691b364d2eac2468131331cf522020-11-24T23:56:27ZengHindawi LimitedBioinorganic Chemistry and Applications1565-36331687-479X2010-01-01201010.1155/2010/104329104329Synthesis and Supramolecular Structure of a (5-(3-(1H-tetrazol-5-yl)phenyl)-1H-tetrazole) Cobalt ComplexGeorge E. Kostakis0Christopher E. Anson1Annie K. Powell2Institute of Nanotechnology, Karlsruhe Institute of Technology, Postfach 3640, 76021 Karlsruhe, GermanyInstitute of Inorganic Chemistry, Karlsruhe Institute of Technology, Engessertsrasse 15, 76131 Karlsruhe, GermanyInstitute of Nanotechnology, Karlsruhe Institute of Technology, Postfach 3640, 76021 Karlsruhe, GermanyThe reaction of CoCl2·6H2O with m-BDTH2 (1,3-benzeneditetrazol-5-yl) leads to [Co(C8H6N8)2(H2O)2(CH3CN)2]Cl2 (1). Both tetrazolic groups remain protonated existing in a 1H tautomeric form. A trifurcated chlorine atom and stacking interactions assemble compound 1 into a three-dimensional network.http://dx.doi.org/10.1155/2010/104329
collection	DOAJ
language	English
format	Article
sources	DOAJ
author	George E. Kostakis Christopher E. Anson Annie K. Powell
spellingShingle	George E. Kostakis Christopher E. Anson Annie K. Powell Synthesis and Supramolecular Structure of a (5-(3-(1H-tetrazol-5-yl)phenyl)-1H-tetrazole) Cobalt Complex Bioinorganic Chemistry and Applications
author_facet	George E. Kostakis Christopher E. Anson Annie K. Powell
author_sort	George E. Kostakis
title	Synthesis and Supramolecular Structure of a (5-(3-(1H-tetrazol-5-yl)phenyl)-1H-tetrazole) Cobalt Complex
title_short	Synthesis and Supramolecular Structure of a (5-(3-(1H-tetrazol-5-yl)phenyl)-1H-tetrazole) Cobalt Complex
title_full	Synthesis and Supramolecular Structure of a (5-(3-(1H-tetrazol-5-yl)phenyl)-1H-tetrazole) Cobalt Complex
title_fullStr	Synthesis and Supramolecular Structure of a (5-(3-(1H-tetrazol-5-yl)phenyl)-1H-tetrazole) Cobalt Complex
title_full_unstemmed	Synthesis and Supramolecular Structure of a (5-(3-(1H-tetrazol-5-yl)phenyl)-1H-tetrazole) Cobalt Complex
title_sort	synthesis and supramolecular structure of a (5-(3-(1h-tetrazol-5-yl)phenyl)-1h-tetrazole) cobalt complex
publisher	Hindawi Limited
series	Bioinorganic Chemistry and Applications
issn	1565-3633 1687-479X
publishDate	2010-01-01
description	The reaction of CoCl2·6H2O with m-BDTH2 (1,3-benzeneditetrazol-5-yl) leads to [Co(C8H6N8)2(H2O)2(CH3CN)2]Cl2 (1). Both tetrazolic groups remain protonated existing in a 1H tautomeric form. A trifurcated chlorine atom and stacking interactions assemble compound 1 into a three-dimensional network.
url	http://dx.doi.org/10.1155/2010/104329
work_keys_str_mv	AT georgeekostakis synthesisandsupramolecularstructureofa531htetrazol5ylphenyl1htetrazolecobaltcomplex AT christophereanson synthesisandsupramolecularstructureofa531htetrazol5ylphenyl1htetrazolecobaltcomplex AT anniekpowell synthesisandsupramolecularstructureofa531htetrazol5ylphenyl1htetrazolecobaltcomplex
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Synthesis and Supramolecular Structure of a (5-(3-(1H-tetrazol-5-yl)phenyl)-1H-tetrazole) Cobalt Complex

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