Synthesis and Supramolecular Structure of a (5-(3-(1H-tetrazol-5-yl)phenyl)-1H-tetrazole) Cobalt Complex
The reaction of CoCl2·6H2O with m-BDTH2 (1,3-benzeneditetrazol-5-yl) leads to [Co(C8H6N8)2(H2O)2(CH3CN)2]Cl2 (1). Both tetrazolic groups remain protonated existing in a 1H tautomeric form. A trifurcated chlorine atom and stacking interactions assemble compound 1 into a three-dimensional network.
| Main Authors: | , , |
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| Format: | Article |
| Language: | English |
| Published: |
Hindawi Limited
2010-01-01
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| Series: | Bioinorganic Chemistry and Applications |
| Online Access: | http://dx.doi.org/10.1155/2010/104329 |
| Summary: | The reaction of CoCl2·6H2O with m-BDTH2 (1,3-benzeneditetrazol-5-yl) leads to [Co(C8H6N8)2(H2O)2(CH3CN)2]Cl2 (1). Both tetrazolic groups remain protonated existing in a 1H tautomeric form. A trifurcated chlorine atom and stacking interactions assemble compound 1 into a three-dimensional network. |
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| ISSN: | 1565-3633 1687-479X |