Monoclinic polymorph of poly[[di-μ-aqua-triaquadi-μ-oxalato-barium(II)copper(II)] monohydrate]

Monoclinic polymorph of poly[[di-μ-aqua-triaquadi-μ-oxalato-barium(II)copper(II)] monohydrate]

A monoclinic polymorph of the title compound, {[BaCu(C2O4)2(H2O)5]·H2O}n, is reported. The structure is best described as a coordination polymer where the CuII and BaII centers are coordinated by five and nine O atoms, respectively, in capped quadratic antiprismatic and tetragonal pyramidal...

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Main Authors: Justin Nenwa, Michel M. Belombe, Boniface P. T. Fokwa, Richard Dronskowski
Format: Article
Language:English
Published: International Union of Crystallography 2008-01-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S1600536807064525
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spelling doaj-e5ea9f8b6dcc4748bb21fdfe0dde540d2020-11-25T02:03:47ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682008-01-01641m116m11710.1107/S1600536807064525Monoclinic polymorph of poly[[di-μ-aqua-triaquadi-μ-oxalato-barium(II)copper(II)] monohydrate]Justin NenwaMichel M. BelombeBoniface P. T. FokwaRichard DronskowskiA monoclinic polymorph of the title compound, {[BaCu(C2O4)2(H2O)5]·H2O}n, is reported. The structure is best described as a coordination polymer where the CuII and BaII centers are coordinated by five and nine O atoms, respectively, in capped quadratic antiprismatic and tetragonal pyramidal geometries. The polymerization arises due to the presence of bridging mono- and bidentate oxalate ligands as well as bridging water molecules. The crystal structure is consolidated by a three-dimensional network of hydrogen bonding.http://scripts.iucr.org/cgi-bin/paper?S1600536807064525
collection DOAJ
language English
format Article
sources DOAJ
author Justin Nenwa
Michel M. Belombe
Boniface P. T. Fokwa
Richard Dronskowski
spellingShingle Justin Nenwa
Michel M. Belombe
Boniface P. T. Fokwa
Richard Dronskowski
Monoclinic polymorph of poly[[di-μ-aqua-triaquadi-μ-oxalato-barium(II)copper(II)] monohydrate]
Acta Crystallographica Section E
author_facet Justin Nenwa
Michel M. Belombe
Boniface P. T. Fokwa
Richard Dronskowski
author_sort Justin Nenwa
title Monoclinic polymorph of poly[[di-μ-aqua-triaquadi-μ-oxalato-barium(II)copper(II)] monohydrate]
title_short Monoclinic polymorph of poly[[di-μ-aqua-triaquadi-μ-oxalato-barium(II)copper(II)] monohydrate]
title_full Monoclinic polymorph of poly[[di-μ-aqua-triaquadi-μ-oxalato-barium(II)copper(II)] monohydrate]
title_fullStr Monoclinic polymorph of poly[[di-μ-aqua-triaquadi-μ-oxalato-barium(II)copper(II)] monohydrate]
title_full_unstemmed Monoclinic polymorph of poly[[di-μ-aqua-triaquadi-μ-oxalato-barium(II)copper(II)] monohydrate]
title_sort monoclinic polymorph of poly[[di-μ-aqua-triaquadi-μ-oxalato-barium(ii)copper(ii)] monohydrate]
publisher International Union of Crystallography
series Acta Crystallographica Section E
issn 1600-5368
publishDate 2008-01-01
description A monoclinic polymorph of the title compound, {[BaCu(C2O4)2(H2O)5]·H2O}n, is reported. The structure is best described as a coordination polymer where the CuII and BaII centers are coordinated by five and nine O atoms, respectively, in capped quadratic antiprismatic and tetragonal pyramidal geometries. The polymerization arises due to the presence of bridging mono- and bidentate oxalate ligands as well as bridging water molecules. The crystal structure is consolidated by a three-dimensional network of hydrogen bonding.
url http://scripts.iucr.org/cgi-bin/paper?S1600536807064525
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AT michelmbelombe monoclinicpolymorphofpolydi956aquatriaquadi956oxalatobariumiicopperiimonohydrate
AT bonifaceptfokwa monoclinicpolymorphofpolydi956aquatriaquadi956oxalatobariumiicopperiimonohydrate
AT richarddronskowski monoclinicpolymorphofpolydi956aquatriaquadi956oxalatobariumiicopperiimonohydrate
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