fac-Aquadichloridotris(tetramethylene sulfoxide-κS)ruthenium(II)
The title molecule, [RuCl2(C4H8OS)3(H2O)], is the isomer with the two chloride ligands cis and the three S-coordinated tetramethylene sulfoxide ligands facial relative to the Ru(II) center. The Ru—Cl distances are 2.4161 (7) and 2.4317 (7) Å, the Ru&a...
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International Union of Crystallography
2009-02-01
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| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536809000439 |
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doaj-e59ac833f793486caecbce01e366c6842020-11-24T22:09:24ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682009-02-01652m170m17010.1107/S1600536809000439fac-Aquadichloridotris(tetramethylene sulfoxide-κS)ruthenium(II)Frank R. FronczekCarlos F. GonzalesRadhey S. SrivastavaThe title molecule, [RuCl2(C4H8OS)3(H2O)], is the isomer with the two chloride ligands cis and the three S-coordinated tetramethylene sulfoxide ligands facial relative to the Ru(II) center. The Ru—Cl distances are 2.4161 (7) and 2.4317 (7) Å, the Ru—O distance is 2.1540 (19) Å, and the Ru—S distances are in the range 2.2254 (8)–2.2657 (7) Å, with the shortest being that trans to the aqua ligand. The coordinated water molecule forms intermolecular hydrogen bonds with Cl and sulfoxide O atoms.http://scripts.iucr.org/cgi-bin/paper?S1600536809000439 |
| collection |
DOAJ |
| language |
English |
| format |
Article |
| sources |
DOAJ |
| author |
Frank R. Fronczek Carlos F. Gonzales Radhey S. Srivastava |
| spellingShingle |
Frank R. Fronczek Carlos F. Gonzales Radhey S. Srivastava fac-Aquadichloridotris(tetramethylene sulfoxide-κS)ruthenium(II) Acta Crystallographica Section E |
| author_facet |
Frank R. Fronczek Carlos F. Gonzales Radhey S. Srivastava |
| author_sort |
Frank R. Fronczek |
| title |
fac-Aquadichloridotris(tetramethylene sulfoxide-κS)ruthenium(II) |
| title_short |
fac-Aquadichloridotris(tetramethylene sulfoxide-κS)ruthenium(II) |
| title_full |
fac-Aquadichloridotris(tetramethylene sulfoxide-κS)ruthenium(II) |
| title_fullStr |
fac-Aquadichloridotris(tetramethylene sulfoxide-κS)ruthenium(II) |
| title_full_unstemmed |
fac-Aquadichloridotris(tetramethylene sulfoxide-κS)ruthenium(II) |
| title_sort |
fac-aquadichloridotris(tetramethylene sulfoxide-κs)ruthenium(ii) |
| publisher |
International Union of Crystallography |
| series |
Acta Crystallographica Section E |
| issn |
1600-5368 |
| publishDate |
2009-02-01 |
| description |
The title molecule, [RuCl2(C4H8OS)3(H2O)], is the isomer with the two chloride ligands cis and the three S-coordinated tetramethylene sulfoxide ligands facial relative to the Ru(II) center. The Ru—Cl distances are 2.4161 (7) and 2.4317 (7) Å, the Ru—O distance is 2.1540 (19) Å, and the Ru—S distances are in the range 2.2254 (8)–2.2657 (7) Å, with the shortest being that trans to the aqua ligand. The coordinated water molecule forms intermolecular hydrogen bonds with Cl and sulfoxide O atoms. |
| url |
http://scripts.iucr.org/cgi-bin/paper?S1600536809000439 |
| work_keys_str_mv |
AT frankrfronczek facaquadichloridotristetramethylenesulfoxide954srutheniumii AT carlosfgonzales facaquadichloridotristetramethylenesulfoxide954srutheniumii AT radheyssrivastava facaquadichloridotristetramethylenesulfoxide954srutheniumii |
| _version_ |
1725812069533483008 |