Quantum cutting properties in KYF4:Tb3+, Yb3+ phosphors: Judd-Ofelt analysis, rate equation models and dynamic processes

• Main Authors: Biao Zheng, Jinquan Hong, Bohao Chen, Ying Chen, Ruoqian Lin, Chunlei Huang, Cheng Zhang, Jun Wang, Lin Lin, Zhiqiang Zheng
• Format: Article
• Language: English
• Published: Elsevier 2021-09-01
• Series: Results in Physics
• Subjects: Spectroscopic properties; Rate equation; Dynamic analysis; Quantum cutting; Energy transfer
• Online Access: http://www.sciencedirect.com/science/article/pii/S2211379721006926

Spectroscopic properties play a significant role during the design and development of novel luminescent materials. In this work, quantum cutting (QC) luminescent materials KYF4:Tb3+,Yb3+ phosphors were successfully synthesized by sol–gel method. The crystal structure, morphology, fluorescence spectra, and decay curves were investigated by X-ray diffractometer (XRD), scanning electron microscope (SEM) and spectrofluorometer. The Judd-Ofelt (J-O) parameters, Ωλ (λ = 2, 4, 6), were directly derived from the emission spectra and decay curves, attributed to the transition intensities of Tb3+ ions were dependent on the J-O parameters. Then, the radiative and nonradiative transition rates, fluorescent branching ratios, cross-relaxation rates and lifetimes of QC luminescence were calculated based on the obtained J-O parameters. Moreover, the rate equation models of QC luminescence were established and the time-dependent population densities in excited levels of Tb3+ ions and Yb3+ ions were simulated. Finally, the dynamic processes of QC luminescence were discussed carefully and the corresponding theoretical quantum efficiency was estimated. Our studies would provide an insight into the QC luminescence and give theoretical guidance for developing novel luminescent materials.