Unexpected Formation and Structural Characterization of a Dinuclear Sodium Half-Sandwich Complex

Unexpected Formation and Structural Characterization of a Dinuclear Sodium Half-Sandwich Complex

Treatment of N,N′-diisopropylcarbodiimide with sodium cyclopentadienide (NaCp) in a molar ratio of 1:1 in THF solution resulted in formation of the unexpected dinuclear sodium half-sandwich complex [NaC5H3{C(NHiPr)(=NiPr)}2-1,2]2 (1) as colorless crystals in low yield. The newly formed lig...

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Bibliographic Details
Main Authors: Nicole Harmgarth, Phil Liebing, Liane Hilfert, Sabine Busse, Frank T. Edelmann
Format: Article
Language:English
Published: MDPI AG 2018-05-01
Series:Inorganics
Subjects:
Sodium
amidinate ligand
cyclopentadienyl
aminofulvene-aldiminate
crystal structure
Online Access:http://www.mdpi.com/2304-6740/6/2/47

Internet

http://www.mdpi.com/2304-6740/6/2/47

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