Removal Efficiency of Textile Dyes from Aqueous Solutions Using Calcined Waste of Eggshells as Eco-friendly Adsorbent: Kinetic and Thermodynamic Studies

This research investigates the removal of textile dyes (Rhodamine B and Alizarin Red S) from aqueous solution by a low-cost adsorbent prepared from eggshell waste. Batch adsorption experiments were conducted in order to determine the effect of different parameters such as pH, dye concentration, cont...

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Main Authors: R. Slimani, I. El Ouahabi, S. Benkaddour, H. Hiyane, M. Essoufy, Y. Achour, S. El Antri, S. Lazar, M. El Haddad
Format: Article
Language:English
Published: Croatian Society of Chemical Engineers 2021-04-01
Series:Chemical and Biochemical Engineering Quarterly
Subjects:
dye
Online Access:http://silverstripe.fkit.hr/cabeq/assets/Uploads/04-1-21.pdf
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spelling doaj-e532bb2dd045421f8baa0dfad5e3e0e92021-04-26T10:31:37ZengCroatian Society of Chemical EngineersChemical and Biochemical Engineering Quarterly0352-95681846-51532021-04-01351435610.15255/CABEQ.2020.1872Removal Efficiency of Textile Dyes from Aqueous Solutions Using Calcined Waste of Eggshells as Eco-friendly Adsorbent: Kinetic and Thermodynamic StudiesR. Slimani0I. El Ouahabi1S. Benkaddour2H. Hiyane3M. Essoufy4Y. Achour5 S. El Antri6 S. Lazar7M. El Haddad8 Laboratory of Spectroscopy, Molecular Modeling, Materials, Nanomaterials, Water & Environment-CERNE2D, Faculty of Sciences, Mohammed V University in Rabat, BP 1014RP, Rabat, Morocco Laboratory of Biochemistry, Environment &Agroalimentary URAC36, Faculty of Sciences and Techniques, Hassan II University of Casablanca, BP 146, 20650, Mohammedia, Morocco Laboratory of Biochemistry, Environment &Agroalimentary URAC36, Faculty of Sciences and Techniques, Hassan II University of Casablanca, BP 146, 20650, Mohammedia, Morocco Laboratory of Biochemistry, Environment &Agroalimentary URAC36, Faculty of Sciences and Techniques, Hassan II University of Casablanca, BP 146, 20650, Mohammedia, Morocco Laboratory of Spectroscopy, Molecular Modeling, Materials, Nanomaterials, Water & Environment-CERNE2D, Faculty of Sciences, Mohammed V University in Rabat, BP 1014RP, Rabat, Morocco Laboratory of Analytical & Molecular Chemistry, Faculty Poly-Disciplinary of Safi, University of Cadi Ayyad, BP4162, 46000 Safi, Morocco Laboratory of Biochemistry, Environment &Agroalimentary URAC36, Faculty of Sciences and Techniques, Hassan II University of Casablanca, BP 146, 20650, Mohammedia, Morocco Laboratory of Biochemistry, Environment &Agroalimentary URAC36, Faculty of Sciences and Techniques, Hassan II University of Casablanca, BP 146, 20650, Mohammedia, Morocco Laboratory of Analytical & Molecular Chemistry, Faculty Poly-Disciplinary of Safi, University of Cadi Ayyad, BP4162, 46000 Safi, MoroccoThis research investigates the removal of textile dyes (Rhodamine B and Alizarin Red S) from aqueous solution by a low-cost adsorbent prepared from eggshell waste. Batch adsorption experiments were conducted in order to determine the effect of different parameters such as pH, dye concentration, contact time, adsorbent dosage, particle size, and temperature. The best correlation was found by Langmuir model, and the maximum adsorption capacity was 175.58 mg g–1 for Rhodamine B and 156.56 mg g–1 for Alizarin Red S. Thermodynamic studies showed that the adsorption of Rhodamine B and Alizarin Red S were feasible, spontaneous, and exothermic in nature. Regeneration study conducted to test the reusability (five cycles) and comparison of adsorption capacities of Rhodamine B and Alizarin Red S showed that calcined eggshell adsorbent could potentially be used for the removal of dyes from aqueous solutions.http://silverstripe.fkit.hr/cabeq/assets/Uploads/04-1-21.pdfcalcined eggshellsdyeadsorptionkineticsisotherms
collection DOAJ
language English
format Article
sources DOAJ
author R. Slimani
I. El Ouahabi
S. Benkaddour
H. Hiyane
M. Essoufy
Y. Achour
S. El Antri
S. Lazar
M. El Haddad
spellingShingle R. Slimani
I. El Ouahabi
S. Benkaddour
H. Hiyane
M. Essoufy
Y. Achour
S. El Antri
S. Lazar
M. El Haddad
Removal Efficiency of Textile Dyes from Aqueous Solutions Using Calcined Waste of Eggshells as Eco-friendly Adsorbent: Kinetic and Thermodynamic Studies
Chemical and Biochemical Engineering Quarterly
calcined eggshells
dye
adsorption
kinetics
isotherms
author_facet R. Slimani
I. El Ouahabi
S. Benkaddour
H. Hiyane
M. Essoufy
Y. Achour
S. El Antri
S. Lazar
M. El Haddad
author_sort R. Slimani
title Removal Efficiency of Textile Dyes from Aqueous Solutions Using Calcined Waste of Eggshells as Eco-friendly Adsorbent: Kinetic and Thermodynamic Studies
title_short Removal Efficiency of Textile Dyes from Aqueous Solutions Using Calcined Waste of Eggshells as Eco-friendly Adsorbent: Kinetic and Thermodynamic Studies
title_full Removal Efficiency of Textile Dyes from Aqueous Solutions Using Calcined Waste of Eggshells as Eco-friendly Adsorbent: Kinetic and Thermodynamic Studies
title_fullStr Removal Efficiency of Textile Dyes from Aqueous Solutions Using Calcined Waste of Eggshells as Eco-friendly Adsorbent: Kinetic and Thermodynamic Studies
title_full_unstemmed Removal Efficiency of Textile Dyes from Aqueous Solutions Using Calcined Waste of Eggshells as Eco-friendly Adsorbent: Kinetic and Thermodynamic Studies
title_sort removal efficiency of textile dyes from aqueous solutions using calcined waste of eggshells as eco-friendly adsorbent: kinetic and thermodynamic studies
publisher Croatian Society of Chemical Engineers
series Chemical and Biochemical Engineering Quarterly
issn 0352-9568
1846-5153
publishDate 2021-04-01
description This research investigates the removal of textile dyes (Rhodamine B and Alizarin Red S) from aqueous solution by a low-cost adsorbent prepared from eggshell waste. Batch adsorption experiments were conducted in order to determine the effect of different parameters such as pH, dye concentration, contact time, adsorbent dosage, particle size, and temperature. The best correlation was found by Langmuir model, and the maximum adsorption capacity was 175.58 mg g–1 for Rhodamine B and 156.56 mg g–1 for Alizarin Red S. Thermodynamic studies showed that the adsorption of Rhodamine B and Alizarin Red S were feasible, spontaneous, and exothermic in nature. Regeneration study conducted to test the reusability (five cycles) and comparison of adsorption capacities of Rhodamine B and Alizarin Red S showed that calcined eggshell adsorbent could potentially be used for the removal of dyes from aqueous solutions.
topic calcined eggshells
dye
adsorption
kinetics
isotherms
url http://silverstripe.fkit.hr/cabeq/assets/Uploads/04-1-21.pdf
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