Oxidation-Induced Detachment of Ruthenoarene Units and Oxygen Insertion in Bis-Pd(II) Hexaphyrin π-Ruthenium Complexes

Oxidation-Induced Detachment of Ruthenoarene Units and Oxygen Insertion in Bis-Pd(II) Hexaphyrin π-Ruthenium Complexes

Two types of new bis-Pd(II) hexaphyrin π-ruthenium complexes are reported. A double-decker bis-Pd(II) hexaphyrin π-ruthenium complex <b>4</b> was obtained by oxidation-induced detachment of a ruthenoarene unit from the triple-decker complex <b>3</b> and oxygen-inserted triple...

Full description

Bibliographic Details
Main Authors: Akito Nakai, Takayuki Tanaka, Atsuhiro Osuka
Format: Article
Language:English
Published: MDPI AG 2020-06-01
Series:Molecules
Subjects:
expanded porphyrin
π-complex
ruthenium complex
aromaticity
Online Access:https://www.mdpi.com/1420-3049/25/12/2753

Internet

https://www.mdpi.com/1420-3049/25/12/2753

Similar Items