Synthesis of TiO2 by the pechini method and photocatalytic degradation of methyl red

• Main Authors: Pollyana Caetano Ribeiro, Ana Cristina Figueiredo de Melo da Costa, Ruth Herta Goldschmidt Aliaga Kiminami, José Marcos Sasaki, Hélio Lucena Lira
• Format: Article
• Language: English
• Published: Associação Brasileira de Metalurgia e Materiais (ABM); Associação Brasileira de Cerâmica (ABC); Associação Brasileira de Polímeros (ABPol) 2012-01-01
• Series: Materials Research
• Subjects: photocatalysis; methyl red dye; titanium dioxide; Pechini method
• Online Access: http://www.scielo.br/scielo.php?script=sci_arttext&pid=S1516-14392012005000176

This work evaluated the catalytic activity of TiO2 synthesized by the Pechini method. with varying molar ratios of 2:1, 3:1 and 4:1 of citric acid/metallic cations, in the photocatalytic degradation of methyl red dye in aqueous solution. The samples were characterized by X-ray diffraction, phase quantification by Rietveld structure refinement, and textural analysis by nitrogen adsorption, and their photocatalytic performance was bench- tested. The results indicated that the 3:1 and 4:1 samples contained two phases, with 84.4 and 89% of anatase phase and 15.6 and 11% of rutile phase, respectively. The 2:1 sample contained only anatase phase. The total discoloration of methyl red dye in 24 hours confirmed the high photocatalytic efficiency of the 2:1 sample, which was ascribed to the formation of monophasic anatase.