1,3-Difluorobenzene

1,3-Difluorobenzene

The weak electrostatic and dispersive forces between C(δ+)—F(δ−) and H(δ+)—C(δ−) are at the borderline of the hydrogen-bond phenomenon and are poorly directional and further deformed in the pr...

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Main Authors: Michael T. Kirchner, Dieter Bläser, Roland Boese, Tejender S. Thakur, Gautam R. Desiraju
Format: Article
Language:English
Published: International Union of Crystallography 2009-11-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S1600536809038987
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spelling doaj-e4b6a00a88aa49e8ae5e762fda96046c2020-11-25T00:48:42ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682009-11-016511o2668o266910.1107/S16005368090389871,3-DifluorobenzeneMichael T. KirchnerDieter BläserRoland BoeseTejender S. ThakurGautam R. DesirajuThe weak electrostatic and dispersive forces between C(δ+)—F(δ−) and H(δ+)—C(δ−) are at the borderline of the hydrogen-bond phenomenon and are poorly directional and further deformed in the presence of other dominant interactions, e.g. C—H...π. The title compound, C6H4F2, Z′ = 2, forms one-dimensional tapes along two homodromic C—H...F hydrogen bonds. The one-dimensional tapes are connected into corrugated two-dimensional sheets by further bi- or trifrucated C—H...F hydrogen bonds. Packing in the third dimension is controlled by C—H...π interactions. http://scripts.iucr.org/cgi-bin/paper?S1600536809038987
collection DOAJ
language English
format Article
sources DOAJ
author Michael T. Kirchner
Dieter Bläser
Roland Boese
Tejender S. Thakur
Gautam R. Desiraju
spellingShingle Michael T. Kirchner
Dieter Bläser
Roland Boese
Tejender S. Thakur
Gautam R. Desiraju
1,3-Difluorobenzene
Acta Crystallographica Section E
author_facet Michael T. Kirchner
Dieter Bläser
Roland Boese
Tejender S. Thakur
Gautam R. Desiraju
author_sort Michael T. Kirchner
title 1,3-Difluorobenzene
title_short 1,3-Difluorobenzene
title_full 1,3-Difluorobenzene
title_fullStr 1,3-Difluorobenzene
title_full_unstemmed 1,3-Difluorobenzene
title_sort 1,3-difluorobenzene
publisher International Union of Crystallography
series Acta Crystallographica Section E
issn 1600-5368
publishDate 2009-11-01
description The weak electrostatic and dispersive forces between C(δ+)—F(δ−) and H(δ+)—C(δ−) are at the borderline of the hydrogen-bond phenomenon and are poorly directional and further deformed in the presence of other dominant interactions, e.g. C—H...π. The title compound, C6H4F2, Z′ = 2, forms one-dimensional tapes along two homodromic C—H...F hydrogen bonds. The one-dimensional tapes are connected into corrugated two-dimensional sheets by further bi- or trifrucated C—H...F hydrogen bonds. Packing in the third dimension is controlled by C—H...π interactions.
url http://scripts.iucr.org/cgi-bin/paper?S1600536809038987
work_keys_str_mv AT michaeltkirchner 13difluorobenzene
AT dieterblamp228ser 13difluorobenzene
AT rolandboese 13difluorobenzene
AT tejendersthakur 13difluorobenzene
AT gautamrdesiraju 13difluorobenzene
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