Selective synthesis of β-unsubstituted meso-aryl substituted tripyrranes in water

A convenient method for the synthesis of β-unsubstituted meso-aryl substituted tripyrranes was developed. Pyrrole condensed with aldehyde in acidic aqueous to produce tripyrranes selectively in moderate yield. The selectivity for tripyrranes depended on the electronic and steric properties of aldehy...

Full description

Bibliographic Details
Main Authors:	Cheng-Zhi Gu, Ya-Qing Feng, Peng-Peng Liu, Shu-Xian Meng
Format:	Article
Language:	English
Published:	Elsevier 2015-03-01
Series:	Journal of Saudi Chemical Society
Subjects:	Tripyrrane Pyrrole Condensation Water Selectivity
Online Access:	http://www.sciencedirect.com/science/article/pii/S1319610314000696

id	doaj-e491b54431194b0080f409d806184484
record_format	Article
spelling	doaj-e491b54431194b0080f409d8061844842020-11-24T23:07:08ZengElsevierJournal of Saudi Chemical Society1319-61032015-03-0119222723210.1016/j.jscs.2014.05.004Selective synthesis of β-unsubstituted meso-aryl substituted tripyrranes in waterCheng-Zhi Gu0Ya-Qing Feng1Peng-Peng Liu2Shu-Xian Meng3School of Chemical Engineering, TianJin University, Tianjin 300072, PR ChinaSchool of Chemical Engineering, TianJin University, Tianjin 300072, PR ChinaSchool of Chemical Engineering, TianJin University, Tianjin 300072, PR ChinaSchool of Chemical Engineering, TianJin University, Tianjin 300072, PR ChinaA convenient method for the synthesis of β-unsubstituted meso-aryl substituted tripyrranes was developed. Pyrrole condensed with aldehyde in acidic aqueous to produce tripyrranes selectively in moderate yield. The selectivity for tripyrranes depended on the electronic and steric properties of aldehyde, the stoichiometric molar ratio and concentrations of the starting materials. The title compounds were isolated and characterized by 1H NMR, 13C NMR and HR-MS analysis.http://www.sciencedirect.com/science/article/pii/S1319610314000696TripyrranePyrroleCondensationWaterSelectivity
collection	DOAJ
language	English
format	Article
sources	DOAJ
author	Cheng-Zhi Gu Ya-Qing Feng Peng-Peng Liu Shu-Xian Meng
spellingShingle	Cheng-Zhi Gu Ya-Qing Feng Peng-Peng Liu Shu-Xian Meng Selective synthesis of β-unsubstituted meso-aryl substituted tripyrranes in water Journal of Saudi Chemical Society Tripyrrane Pyrrole Condensation Water Selectivity
author_facet	Cheng-Zhi Gu Ya-Qing Feng Peng-Peng Liu Shu-Xian Meng
author_sort	Cheng-Zhi Gu
title	Selective synthesis of β-unsubstituted meso-aryl substituted tripyrranes in water
title_short	Selective synthesis of β-unsubstituted meso-aryl substituted tripyrranes in water
title_full	Selective synthesis of β-unsubstituted meso-aryl substituted tripyrranes in water
title_fullStr	Selective synthesis of β-unsubstituted meso-aryl substituted tripyrranes in water
title_full_unstemmed	Selective synthesis of β-unsubstituted meso-aryl substituted tripyrranes in water
title_sort	selective synthesis of β-unsubstituted meso-aryl substituted tripyrranes in water
publisher	Elsevier
series	Journal of Saudi Chemical Society
issn	1319-6103
publishDate	2015-03-01
description	A convenient method for the synthesis of β-unsubstituted meso-aryl substituted tripyrranes was developed. Pyrrole condensed with aldehyde in acidic aqueous to produce tripyrranes selectively in moderate yield. The selectivity for tripyrranes depended on the electronic and steric properties of aldehyde, the stoichiometric molar ratio and concentrations of the starting materials. The title compounds were isolated and characterized by 1H NMR, 13C NMR and HR-MS analysis.
topic	Tripyrrane Pyrrole Condensation Water Selectivity
url	http://www.sciencedirect.com/science/article/pii/S1319610314000696
work_keys_str_mv	AT chengzhigu selectivesynthesisofbunsubstitutedmesoarylsubstitutedtripyrranesinwater AT yaqingfeng selectivesynthesisofbunsubstitutedmesoarylsubstitutedtripyrranesinwater AT pengpengliu selectivesynthesisofbunsubstitutedmesoarylsubstitutedtripyrranesinwater AT shuxianmeng selectivesynthesisofbunsubstitutedmesoarylsubstitutedtripyrranesinwater
_version_	1725619841097793536

Selective synthesis of β-unsubstituted meso-aryl substituted tripyrranes in water

Similar Items