Synthesis and characterization of labile ylide of 1-(p-tolyl)-2-(tri-p-tolylphosphoranylidene)ethanone and its related complexes with mercury(II) halides

Synthesis and characterization of labile ylide of 1-(p-tolyl)-2-(tri-p-tolylphosphoranylidene)ethanone and its related complexes with mercury(II) halides

The novel α-phosphorus labile ylide of 1-(p-tolyl)-2-(tri-p-tolylphosphoranylidene)ethanone (PTTPPY) is prepared by the reaction of 2-bromo-1-(p-tolyl)ethanone with tri-p-tolylphosphine in chloroform as solvent. The complexes of the type [HgX2(p-tolyl)3PCHCOC6H4CH3)] (X = Cl, Br and I) are prepared...

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Main Authors: Alireza Dadrass, Shahla Ebrahimnezhad, Mahsa Pourmirza, Ahmad Poursattar Marjani
Format: Article
Language:English
Published: Growing Science 2014-03-01
Series:Current Chemistry Letters
Subjects:
Carbonyl stabilized phosphorus ylide
Mercury(II) halide complexes
Tri-p-tolylphosphine
Keto ylides
Ambidentate ligand
Online Access:http://www.growingscience.com/ccl/Vol3/ccl_2013_30.pdf
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spelling doaj-e48d2d8bdfe84421a183087a03758cd02020-11-25T00:57:55ZengGrowing ScienceCurrent Chemistry Letters1927-72961927-730X2014-03-013210310810.5267/j.ccl.2013.12.002Synthesis and characterization of labile ylide of 1-(p-tolyl)-2-(tri-p-tolylphosphoranylidene)ethanone and its related complexes with mercury(II) halidesAlireza Dadrass Shahla EbrahimnezhadMahsa PourmirzaAhmad Poursattar MarjaniThe novel α-phosphorus labile ylide of 1-(p-tolyl)-2-(tri-p-tolylphosphoranylidene)ethanone (PTTPPY) is prepared by the reaction of 2-bromo-1-(p-tolyl)ethanone with tri-p-tolylphosphine in chloroform as solvent. The complexes of the type [HgX2(p-tolyl)3PCHCOC6H4CH3)] (X = Cl, Br and I) are prepared by the reaction of title ylide with mercury(II) halides in good yields, using methanol as solvent. The final products were characterized by IR, 1H, 13C, 31P NMR spectroscopic methods and microanalysis.http://www.growingscience.com/ccl/Vol3/ccl_2013_30.pdfCarbonyl stabilized phosphorus ylideMercury(II) halide complexesTri-p-tolylphosphineKeto ylidesAmbidentate ligand
collection DOAJ
language English
format Article
sources DOAJ
author Alireza Dadrass
Shahla Ebrahimnezhad
Mahsa Pourmirza
Ahmad Poursattar Marjani
spellingShingle Alireza Dadrass
Shahla Ebrahimnezhad
Mahsa Pourmirza
Ahmad Poursattar Marjani
Synthesis and characterization of labile ylide of 1-(p-tolyl)-2-(tri-p-tolylphosphoranylidene)ethanone and its related complexes with mercury(II) halides
Current Chemistry Letters
Carbonyl stabilized phosphorus ylide
Mercury(II) halide complexes
Tri-p-tolylphosphine
Keto ylides
Ambidentate ligand
author_facet Alireza Dadrass
Shahla Ebrahimnezhad
Mahsa Pourmirza
Ahmad Poursattar Marjani
author_sort Alireza Dadrass
title Synthesis and characterization of labile ylide of 1-(p-tolyl)-2-(tri-p-tolylphosphoranylidene)ethanone and its related complexes with mercury(II) halides
title_short Synthesis and characterization of labile ylide of 1-(p-tolyl)-2-(tri-p-tolylphosphoranylidene)ethanone and its related complexes with mercury(II) halides
title_full Synthesis and characterization of labile ylide of 1-(p-tolyl)-2-(tri-p-tolylphosphoranylidene)ethanone and its related complexes with mercury(II) halides
title_fullStr Synthesis and characterization of labile ylide of 1-(p-tolyl)-2-(tri-p-tolylphosphoranylidene)ethanone and its related complexes with mercury(II) halides
title_full_unstemmed Synthesis and characterization of labile ylide of 1-(p-tolyl)-2-(tri-p-tolylphosphoranylidene)ethanone and its related complexes with mercury(II) halides
title_sort synthesis and characterization of labile ylide of 1-(p-tolyl)-2-(tri-p-tolylphosphoranylidene)ethanone and its related complexes with mercury(ii) halides
publisher Growing Science
series Current Chemistry Letters
issn 1927-7296
1927-730X
publishDate 2014-03-01
description The novel α-phosphorus labile ylide of 1-(p-tolyl)-2-(tri-p-tolylphosphoranylidene)ethanone (PTTPPY) is prepared by the reaction of 2-bromo-1-(p-tolyl)ethanone with tri-p-tolylphosphine in chloroform as solvent. The complexes of the type [HgX2(p-tolyl)3PCHCOC6H4CH3)] (X = Cl, Br and I) are prepared by the reaction of title ylide with mercury(II) halides in good yields, using methanol as solvent. The final products were characterized by IR, 1H, 13C, 31P NMR spectroscopic methods and microanalysis.
topic Carbonyl stabilized phosphorus ylide
Mercury(II) halide complexes
Tri-p-tolylphosphine
Keto ylides
Ambidentate ligand
url http://www.growingscience.com/ccl/Vol3/ccl_2013_30.pdf
work_keys_str_mv AT alirezadadrass synthesisandcharacterizationoflabileylideof1ptolyl2triptolylphosphoranylideneethanoneanditsrelatedcomplexeswithmercuryiihalides
AT shahlaebrahimnezhad synthesisandcharacterizationoflabileylideof1ptolyl2triptolylphosphoranylideneethanoneanditsrelatedcomplexeswithmercuryiihalides
AT mahsapourmirza synthesisandcharacterizationoflabileylideof1ptolyl2triptolylphosphoranylideneethanoneanditsrelatedcomplexeswithmercuryiihalides
AT ahmadpoursattarmarjani synthesisandcharacterizationoflabileylideof1ptolyl2triptolylphosphoranylideneethanoneanditsrelatedcomplexeswithmercuryiihalides
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