Tetrakis(μ2-2-phenoxypropionato)-κ3O,O′:O′;κ3O:O,O′;κ4O:O′-bis[(1,10-phenanthroline-κ2N,N′)(2-phenoxypropionato-κ2O,O′)lanthanum(III)]

Tetrakis(μ2-2-phenoxypropionato)-κ3O,O′:O′;κ3O:O,O′;κ4O:O′-bis[(1,10-phenanthroline-κ2N,N′)(2-phenoxypropionato-κ2O,O′)lanthanum(III)]

In the centrosymmetric binuclear title complex, [La2(C9H9O3)6(C12H8N2)2], the two La(III) ions are linked by four 2-phenoxypropionate (L) groups in bi- and tridentate bridging modes. Each LaIII ion is nine-coordinated by one 1,10-phenanthroline molecule, one bidentate chelating carboxylate group and...

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Main Authors: Guo-Liang Zhao, Jia-Lu Liu, Jin-Bei Shen
Format: Article
Language:English
Published: International Union of Crystallography 2011-10-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S1600536811036117
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spelling doaj-e42644bdeefe41c3ad4ed79ead45172f2020-11-25T01:14:21ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682011-10-016710m1358m135810.1107/S1600536811036117Tetrakis(μ2-2-phenoxypropionato)-κ3O,O′:O′;κ3O:O,O′;κ4O:O′-bis[(1,10-phenanthroline-κ2N,N′)(2-phenoxypropionato-κ2O,O′)lanthanum(III)]Guo-Liang ZhaoJia-Lu LiuJin-Bei ShenIn the centrosymmetric binuclear title complex, [La2(C9H9O3)6(C12H8N2)2], the two La(III) ions are linked by four 2-phenoxypropionate (L) groups in bi- and tridentate bridging modes. Each LaIII ion is nine-coordinated by one 1,10-phenanthroline molecule, one bidentate chelating carboxylate group and four bridging carboxylate groups in a distorted LaN2O7 monocapped square-antiprismatic geometry.http://scripts.iucr.org/cgi-bin/paper?S1600536811036117
collection DOAJ
language English
format Article
sources DOAJ
author Guo-Liang Zhao
Jia-Lu Liu
Jin-Bei Shen
spellingShingle Guo-Liang Zhao
Jia-Lu Liu
Jin-Bei Shen
Tetrakis(μ2-2-phenoxypropionato)-κ3O,O′:O′;κ3O:O,O′;κ4O:O′-bis[(1,10-phenanthroline-κ2N,N′)(2-phenoxypropionato-κ2O,O′)lanthanum(III)]
Acta Crystallographica Section E
author_facet Guo-Liang Zhao
Jia-Lu Liu
Jin-Bei Shen
author_sort Guo-Liang Zhao
title Tetrakis(μ2-2-phenoxypropionato)-κ3O,O′:O′;κ3O:O,O′;κ4O:O′-bis[(1,10-phenanthroline-κ2N,N′)(2-phenoxypropionato-κ2O,O′)lanthanum(III)]
title_short Tetrakis(μ2-2-phenoxypropionato)-κ3O,O′:O′;κ3O:O,O′;κ4O:O′-bis[(1,10-phenanthroline-κ2N,N′)(2-phenoxypropionato-κ2O,O′)lanthanum(III)]
title_full Tetrakis(μ2-2-phenoxypropionato)-κ3O,O′:O′;κ3O:O,O′;κ4O:O′-bis[(1,10-phenanthroline-κ2N,N′)(2-phenoxypropionato-κ2O,O′)lanthanum(III)]
title_fullStr Tetrakis(μ2-2-phenoxypropionato)-κ3O,O′:O′;κ3O:O,O′;κ4O:O′-bis[(1,10-phenanthroline-κ2N,N′)(2-phenoxypropionato-κ2O,O′)lanthanum(III)]
title_full_unstemmed Tetrakis(μ2-2-phenoxypropionato)-κ3O,O′:O′;κ3O:O,O′;κ4O:O′-bis[(1,10-phenanthroline-κ2N,N′)(2-phenoxypropionato-κ2O,O′)lanthanum(III)]
title_sort tetrakis(μ2-2-phenoxypropionato)-κ3o,o′:o′;κ3o:o,o′;κ4o:o′-bis[(1,10-phenanthroline-κ2n,n′)(2-phenoxypropionato-κ2o,o′)lanthanum(iii)]
publisher International Union of Crystallography
series Acta Crystallographica Section E
issn 1600-5368
publishDate 2011-10-01
description In the centrosymmetric binuclear title complex, [La2(C9H9O3)6(C12H8N2)2], the two La(III) ions are linked by four 2-phenoxypropionate (L) groups in bi- and tridentate bridging modes. Each LaIII ion is nine-coordinated by one 1,10-phenanthroline molecule, one bidentate chelating carboxylate group and four bridging carboxylate groups in a distorted LaN2O7 monocapped square-antiprismatic geometry.
url http://scripts.iucr.org/cgi-bin/paper?S1600536811036117
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