Benzyl N′-benzhydrylidenehydrazinecarbodithioate

Benzyl N′-benzhydrylidenehydrazinecarbodithioate

In the title molecule, C21H18N2S2, the C=N—N angle of 117.6 (2)° is significantly smaller than the ideal value of 120° expected for sp2-hybridized N atoms. This is probably a consequence of repulsion between the nitrogen lone pairs and the adjacent N atom, as su...

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Main Author: Bing-Xiang Zhang
Format: Article
Language:English
Published: International Union of Crystallography 2008-12-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S1600536808039408
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spelling doaj-e3d48b5f07b04d49935549e34ec882ed2020-11-25T00:49:44ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682008-12-016412o2477o247710.1107/S1600536808039408Benzyl N′-benzhydrylidenehydrazinecarbodithioateBing-Xiang ZhangIn the title molecule, C21H18N2S2, the C=N—N angle of 117.6 (2)° is significantly smaller than the ideal value of 120° expected for sp2-hybridized N atoms. This is probably a consequence of repulsion between the nitrogen lone pairs and the adjacent N atom, as suggested in Zheng, Qiu, Lin & Liu [Acta Cryst. (2006), E62, o1913–o1914]. The two neighbouring benzene rings form a dihedral angle of 75.95 (3)° with each other, while subtending dihedral angles of 84.18 (3) and 8.44 (2)° with the third ring in the structure.http://scripts.iucr.org/cgi-bin/paper?S1600536808039408
collection DOAJ
language English
format Article
sources DOAJ
author Bing-Xiang Zhang
spellingShingle Bing-Xiang Zhang
Benzyl N′-benzhydrylidenehydrazinecarbodithioate
Acta Crystallographica Section E
author_facet Bing-Xiang Zhang
author_sort Bing-Xiang Zhang
title Benzyl N′-benzhydrylidenehydrazinecarbodithioate
title_short Benzyl N′-benzhydrylidenehydrazinecarbodithioate
title_full Benzyl N′-benzhydrylidenehydrazinecarbodithioate
title_fullStr Benzyl N′-benzhydrylidenehydrazinecarbodithioate
title_full_unstemmed Benzyl N′-benzhydrylidenehydrazinecarbodithioate
title_sort benzyl n′-benzhydrylidenehydrazinecarbodithioate
publisher International Union of Crystallography
series Acta Crystallographica Section E
issn 1600-5368
publishDate 2008-12-01
description In the title molecule, C21H18N2S2, the C=N—N angle of 117.6 (2)° is significantly smaller than the ideal value of 120° expected for sp2-hybridized N atoms. This is probably a consequence of repulsion between the nitrogen lone pairs and the adjacent N atom, as suggested in Zheng, Qiu, Lin & Liu [Acta Cryst. (2006), E62, o1913–o1914]. The two neighbouring benzene rings form a dihedral angle of 75.95 (3)° with each other, while subtending dihedral angles of 84.18 (3) and 8.44 (2)° with the third ring in the structure.
url http://scripts.iucr.org/cgi-bin/paper?S1600536808039408
work_keys_str_mv AT bingxiangzhang benzyln8242benzhydrylidenehydrazinecarbodithioate
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