Crystal structure of 1,1′-bis[1,7-dicarba-closo-dodecaborane(11)]

Crystal structure of 1,1′-bis[1,7-dicarba-closo-dodecaborane(11)]

In the title compound, C4H22B20, the two {1,7-closo-C2B10H11} cages are linked across a centre of inversion, with C—C = 1.5401 (16) Å. The position of the second non-linking cage C atom was established unambiguously by geometric and crystallographic methods and there is no evidence of C/B disorder....

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Main Authors: Lisa Elrick, Georgina M. Rosair, Alan J. Welch
Format: Article
Language:English
Published: International Union of Crystallography 2014-11-01
Series:Acta Crystallographica Section E
Subjects:
crystal structure
carboranes
closo-dodecaborane(11)
Online Access:http://scripts.iucr.org/cgi-bin/paper?S1600536814022132
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spelling doaj-e35e90f1134849bb9dd87b07028929fe2020-11-24T21:22:16ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682014-11-01701137637810.1107/S1600536814022132hb7290Crystal structure of 1,1′-bis[1,7-dicarba-closo-dodecaborane(11)]Lisa Elrick0Georgina M. Rosair1Alan J. Welch2Institute of Chemical Sciences, School of Engineering & Physical Sciences, Heriot-Watt University, Edinburgh EH14 4AS, ScotlandInstitute of Chemical Sciences, School of Engineering & Physical Sciences, Heriot-Watt University, Edinburgh EH14 4AS, ScotlandInstitute of Chemical Sciences, School of Engineering & Physical Sciences, Heriot-Watt University, Edinburgh EH14 4AS, ScotlandIn the title compound, C4H22B20, the two {1,7-closo-C2B10H11} cages are linked across a centre of inversion, with C—C = 1.5401 (16) Å. The position of the second non-linking cage C atom was established unambiguously by geometric and crystallographic methods and there is no evidence of C/B disorder.http://scripts.iucr.org/cgi-bin/paper?S1600536814022132crystal structurecarboranescloso-dodecaborane(11)
collection DOAJ
language English
format Article
sources DOAJ
author Lisa Elrick
Georgina M. Rosair
Alan J. Welch
spellingShingle Lisa Elrick
Georgina M. Rosair
Alan J. Welch
Crystal structure of 1,1′-bis[1,7-dicarba-closo-dodecaborane(11)]
Acta Crystallographica Section E
crystal structure
carboranes
closo-dodecaborane(11)
author_facet Lisa Elrick
Georgina M. Rosair
Alan J. Welch
author_sort Lisa Elrick
title Crystal structure of 1,1′-bis[1,7-dicarba-closo-dodecaborane(11)]
title_short Crystal structure of 1,1′-bis[1,7-dicarba-closo-dodecaborane(11)]
title_full Crystal structure of 1,1′-bis[1,7-dicarba-closo-dodecaborane(11)]
title_fullStr Crystal structure of 1,1′-bis[1,7-dicarba-closo-dodecaborane(11)]
title_full_unstemmed Crystal structure of 1,1′-bis[1,7-dicarba-closo-dodecaborane(11)]
title_sort crystal structure of 1,1′-bis[1,7-dicarba-closo-dodecaborane(11)]
publisher International Union of Crystallography
series Acta Crystallographica Section E
issn 1600-5368
publishDate 2014-11-01
description In the title compound, C4H22B20, the two {1,7-closo-C2B10H11} cages are linked across a centre of inversion, with C—C = 1.5401 (16) Å. The position of the second non-linking cage C atom was established unambiguously by geometric and crystallographic methods and there is no evidence of C/B disorder.
topic crystal structure
carboranes
closo-dodecaborane(11)
url http://scripts.iucr.org/cgi-bin/paper?S1600536814022132
work_keys_str_mv AT lisaelrick crystalstructureof11bis17dicarbaclosododecaborane11
AT georginamrosair crystalstructureof11bis17dicarbaclosododecaborane11
AT alanjwelch crystalstructureof11bis17dicarbaclosododecaborane11
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