Bis[2-(1H-benzimidazol-2-yl)acetato-κ2N3,O]bis(ethanol-κO)nickel(II)
In the title compound, [Ni(C9H7N2O2)2(C2H5OH)2], the NiII ion is situated on an inversion center and is coordinated by two N and two O atoms from two 2-(1H-benzimidazol-2-yl)acetate (L) ligands and by two O atoms from two ethanol ligands in a distorted octahedral geometry. In the L ligand, the aceta...
| Main Authors: | , |
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| Format: | Article |
| Language: | English |
| Published: |
International Union of Crystallography
2012-12-01
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| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S160053681204514X |
| Summary: | In the title compound, [Ni(C9H7N2O2)2(C2H5OH)2], the NiII ion is situated on an inversion center and is coordinated by two N and two O atoms from two 2-(1H-benzimidazol-2-yl)acetate (L) ligands and by two O atoms from two ethanol ligands in a distorted octahedral geometry. In the L ligand, the acetate group deviates significantly from the benzimidazole plane, the C—C—C—O(coordinating) torsion angle being 34.2 (5)°. In the crystal, O—H...O and N—H...O hydrogen bonds link the molecules into a two-dimensional supramolecular network parallel to the bc plane. |
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| ISSN: | 1600-5368 |