Diphenyl (methylamido)phosphate

The N—H bond in the title compound, C13H14NO3P, is syn-oriented relative to the P=O bond. The N atom deviates somewhat from planarity, the sum of the bond angles being 353.3°. The P atom has a distorted tetrahedral coordination; its bond angles are in the range 93.96&a...

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Bibliographic Details
Main Authors: Fahimeh Sabbaghi, Mehrdad Pourayoubi, Marek Nečas, Peter Bartoš
Format: Article
Language:English
Published: International Union of Crystallography 2012-10-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S160053681203869X
Description
Summary:The N—H bond in the title compound, C13H14NO3P, is syn-oriented relative to the P=O bond. The N atom deviates somewhat from planarity, the sum of the bond angles being 353.3°. The P atom has a distorted tetrahedral coordination; its bond angles are in the range 93.96 (5)–116.83 (6)°. In the crystal, molecules form centrosymmetric dimers through P=O...H—N hydrogen bonds.
ISSN:1600-5368