Tetramethylammonium aquatrichloridooxalatostannate(IV) monohydrate

Tetramethylammonium aquatrichloridooxalatostannate(IV) monohydrate

The SnIV atom in the title compound, [(CH3)4N][Sn(C2O4)Cl3(H2O)]·H2O, obtained from the reaction between SnCl4 and [(CH3)4N]2C2O4·2H2O, is six-coordinated by three Cl atoms, an O atom of a water molecule and two O atoms from an asymmetrically chelating oxalate anion. The environmen...

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Main Authors: Yaya Sow, Libasse Diop, Kieran C. Molloy, Gabriele Kociok-Köhn
Format: Article
Language:English
Published: International Union of Crystallography 2013-02-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S1600536813000895
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spelling doaj-e2741206f9884a40bc96d84a0d42a32c2020-11-25T00:54:34ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682013-02-01692m106m10710.1107/S1600536813000895Tetramethylammonium aquatrichloridooxalatostannate(IV) monohydrateYaya SowLibasse DiopKieran C. MolloyGabriele Kociok-KöhnThe SnIV atom in the title compound, [(CH3)4N][Sn(C2O4)Cl3(H2O)]·H2O, obtained from the reaction between SnCl4 and [(CH3)4N]2C2O4·2H2O, is six-coordinated by three Cl atoms, an O atom of a water molecule and two O atoms from an asymmetrically chelating oxalate anion. The environment around the SnIV atom is distorted octahedral. The anions are connected by the lattice water molecule through O—H...O hydrogen bonds, leading to a layered structure parallel to (010). The cations are located between these layers and besides Coulombic forces are connected to the anionic layers through weak C—H...O and C—H...Cl interactions.http://scripts.iucr.org/cgi-bin/paper?S1600536813000895
collection DOAJ
language English
format Article
sources DOAJ
author Yaya Sow
Libasse Diop
Kieran C. Molloy
Gabriele Kociok-Köhn
spellingShingle Yaya Sow
Libasse Diop
Kieran C. Molloy
Gabriele Kociok-Köhn
Tetramethylammonium aquatrichloridooxalatostannate(IV) monohydrate
Acta Crystallographica Section E
author_facet Yaya Sow
Libasse Diop
Kieran C. Molloy
Gabriele Kociok-Köhn
author_sort Yaya Sow
title Tetramethylammonium aquatrichloridooxalatostannate(IV) monohydrate
title_short Tetramethylammonium aquatrichloridooxalatostannate(IV) monohydrate
title_full Tetramethylammonium aquatrichloridooxalatostannate(IV) monohydrate
title_fullStr Tetramethylammonium aquatrichloridooxalatostannate(IV) monohydrate
title_full_unstemmed Tetramethylammonium aquatrichloridooxalatostannate(IV) monohydrate
title_sort tetramethylammonium aquatrichloridooxalatostannate(iv) monohydrate
publisher International Union of Crystallography
series Acta Crystallographica Section E
issn 1600-5368
publishDate 2013-02-01
description The SnIV atom in the title compound, [(CH3)4N][Sn(C2O4)Cl3(H2O)]·H2O, obtained from the reaction between SnCl4 and [(CH3)4N]2C2O4·2H2O, is six-coordinated by three Cl atoms, an O atom of a water molecule and two O atoms from an asymmetrically chelating oxalate anion. The environment around the SnIV atom is distorted octahedral. The anions are connected by the lattice water molecule through O—H...O hydrogen bonds, leading to a layered structure parallel to (010). The cations are located between these layers and besides Coulombic forces are connected to the anionic layers through weak C—H...O and C—H...Cl interactions.
url http://scripts.iucr.org/cgi-bin/paper?S1600536813000895
work_keys_str_mv AT yayasow tetramethylammoniumaquatrichloridooxalatostannateivmonohydrate
AT libassediop tetramethylammoniumaquatrichloridooxalatostannateivmonohydrate
AT kierancmolloy tetramethylammoniumaquatrichloridooxalatostannateivmonohydrate
AT gabrielekociokk246hn tetramethylammoniumaquatrichloridooxalatostannateivmonohydrate
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