Mechanism of deactivation processes of excited iron(III) thiocyanato complexes with benacen-type ligands
The complexes [Fe(4-R-benacen)(CH3OH)(NCS)], where 4-R-benacen2− are tetradentate open-chain N,N′-ethylenebis(4-R-benzoylacetoneiminato) N2O2-ligands (R=H, Cl, Br, OCH3), are redox stable in the dark in methanolic solutions. Irradiation of the complexes into intraligand and/or ligand-to-metal charge...
| Main Authors: | , , |
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| Format: | Article |
| Language: | English |
| Published: |
Hindawi Limited
2006-01-01
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| Series: | International Journal of Photoenergy |
| Online Access: | http://dx.doi.org/10.1155/IJP/2006/78234 |