Poly[bis(μ2-benzyloxyacetato-κ3O,O′:O′′)cadmium(II)]

Poly[bis(μ2-benzyloxyacetato-κ3O,O′:O′′)cadmium(II)]

The title cadmium derivative of benzyloxyacetic acid, [Cd(C9H9O3)2]n, exists as a μ2-carboxylate-bridged layer network. Two benzyloxyacetate units each chelate the metal through a carboxylate as well as through the ether O atoms; the metal is also coordinated by the double-bond carbonyl O a...

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Bibliographic Details
Main Authors: Seik Weng Ng, Ji-Wei Liu
Format: Article
Language:English
Published: International Union of Crystallography 2008-05-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S1600536808010799
Description
Summary:The title cadmium derivative of benzyloxyacetic acid, [Cd(C9H9O3)2]n, exists as a μ2-carboxylate-bridged layer network. Two benzyloxyacetate units each chelate the metal through a carboxylate as well as through the ether O atoms; the metal is also coordinated by the double-bond carbonyl O atom of two adjacent benzyloxyacetate units in an octahedral geometry. The metal atom lies on a special position of 2 site symmetry. The phenyl group is disordered equally over two positions.
ISSN:1600-5368

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