Synthesis and Thermal Degradation Kinetics of Co(II), Ni(II), Cd(II), Zn(II), Pd(II), Rh(III) and Ru(III) Complexes with Methylquinolino[3,2-b]benzodiazepine

Synthesis and Thermal Degradation Kinetics of Co(II), Ni(II), Cd(II), Zn(II), Pd(II), Rh(III) and Ru(III) Complexes with Methylquinolino[3,2-b]benzodiazepine

A series of new complexes formed by the interaction of a new ligand Methylquinolino[3,2-b]benzodiazepine (L) with various transition metal ions have been isolated and characterized by elemental analysis and electronic, IR, magnetic moment and conductivity measurements. Thermogravimetric (TG) studies...

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Main Authors: Bennehalli Basavaraju, Halehatti S. Bhojya Naik
Format: Article
Language:English
Published: Hindawi Limited 2007-01-01
Series:E-Journal of Chemistry
Online Access:http://dx.doi.org/10.1155/2007/808902
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spelling doaj-e1bc4c37115c4ab295e72dfa3acc33fd2020-11-24T22:42:48ZengHindawi LimitedE-Journal of Chemistry0973-49452090-98102007-01-014219920710.1155/2007/808902Synthesis and Thermal Degradation Kinetics of Co(II), Ni(II), Cd(II), Zn(II), Pd(II), Rh(III) and Ru(III) Complexes with Methylquinolino[3,2-b]benzodiazepineBennehalli Basavaraju0Halehatti S. Bhojya Naik1Department of Biotechnology, GM Institute of Technology, Davangere-577 006, Karnataka, IndiaDepartment of PG studies and Research in Industrial Chemistry, School of Chemical Sciences, Kuvempu University, Shankaraghatta-577451, Shimoga, Karnataka, IndiaA series of new complexes formed by the interaction of a new ligand Methylquinolino[3,2-b]benzodiazepine (L) with various transition metal ions have been isolated and characterized by elemental analysis and electronic, IR, magnetic moment and conductivity measurements. Thermogravimetric (TG) studies of the complexes have been performed in order to establish the mode of their thermal degradation. The thermal degradation was found to proceed in two steps. The kinetics and thermodynamic parameters were computed from the thermal decomposition data.http://dx.doi.org/10.1155/2007/808902
collection DOAJ
language English
format Article
sources DOAJ
author Bennehalli Basavaraju
Halehatti S. Bhojya Naik
spellingShingle Bennehalli Basavaraju
Halehatti S. Bhojya Naik
Synthesis and Thermal Degradation Kinetics of Co(II), Ni(II), Cd(II), Zn(II), Pd(II), Rh(III) and Ru(III) Complexes with Methylquinolino[3,2-b]benzodiazepine
E-Journal of Chemistry
author_facet Bennehalli Basavaraju
Halehatti S. Bhojya Naik
author_sort Bennehalli Basavaraju
title Synthesis and Thermal Degradation Kinetics of Co(II), Ni(II), Cd(II), Zn(II), Pd(II), Rh(III) and Ru(III) Complexes with Methylquinolino[3,2-b]benzodiazepine
title_short Synthesis and Thermal Degradation Kinetics of Co(II), Ni(II), Cd(II), Zn(II), Pd(II), Rh(III) and Ru(III) Complexes with Methylquinolino[3,2-b]benzodiazepine
title_full Synthesis and Thermal Degradation Kinetics of Co(II), Ni(II), Cd(II), Zn(II), Pd(II), Rh(III) and Ru(III) Complexes with Methylquinolino[3,2-b]benzodiazepine
title_fullStr Synthesis and Thermal Degradation Kinetics of Co(II), Ni(II), Cd(II), Zn(II), Pd(II), Rh(III) and Ru(III) Complexes with Methylquinolino[3,2-b]benzodiazepine
title_full_unstemmed Synthesis and Thermal Degradation Kinetics of Co(II), Ni(II), Cd(II), Zn(II), Pd(II), Rh(III) and Ru(III) Complexes with Methylquinolino[3,2-b]benzodiazepine
title_sort synthesis and thermal degradation kinetics of co(ii), ni(ii), cd(ii), zn(ii), pd(ii), rh(iii) and ru(iii) complexes with methylquinolino[3,2-b]benzodiazepine
publisher Hindawi Limited
series E-Journal of Chemistry
issn 0973-4945
2090-9810
publishDate 2007-01-01
description A series of new complexes formed by the interaction of a new ligand Methylquinolino[3,2-b]benzodiazepine (L) with various transition metal ions have been isolated and characterized by elemental analysis and electronic, IR, magnetic moment and conductivity measurements. Thermogravimetric (TG) studies of the complexes have been performed in order to establish the mode of their thermal degradation. The thermal degradation was found to proceed in two steps. The kinetics and thermodynamic parameters were computed from the thermal decomposition data.
url http://dx.doi.org/10.1155/2007/808902
work_keys_str_mv AT bennehallibasavaraju synthesisandthermaldegradationkineticsofcoiiniiicdiizniipdiirhiiiandruiiicomplexeswithmethylquinolino32bbenzodiazepine
AT halehattisbhojyanaik synthesisandthermaldegradationkineticsofcoiiniiicdiizniipdiirhiiiandruiiicomplexeswithmethylquinolino32bbenzodiazepine
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