Titanium(III, IV)-Containing Catalytic Systems for Production of Ultrahigh Molecular Weight Polyethylene Nascent Reactor Powders, Suitable for Solventless Processing—Impact of Oxidation States of Transition Metal

Titanium(III, IV)-Containing Catalytic Systems for Production of Ultrahigh Molecular Weight Polyethylene Nascent Reactor Powders, Suitable for Solventless Processing—Impact of Oxidation States of Transition Metal

Catalytic systems containing TiCl4 or TiCl3, THF, organomagnesium (n-Bu2Mg) and organoaluminum compounds capable of producing ultrahigh molecular weight polyethylene (UHMWPE) were developed. The resulting polymers were characterized by a molecular weight in the range of (1.8–7.8) × 106 Da and desira...

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Bibliographic Details
Main Authors: Vladislav A. Tuskaev, Svetlana C. Gagieva, Dmitrii A. Kurmaev, Nikolay A. Kolosov, Elena S. Mikhaylik, Evgenii K. Golubev, Alexander I. Sizov, Sergey V. Zubkevich, Viktor G. Vasil’ev, Galina G. Nikiforova, Mikhail I. Buzin, Olga A. Serenko, Boris M. Bulychev
Format: Article
Language:English
Published: MDPI AG 2017-12-01
Series:Polymers
Subjects:
Ziegler–Natta polymerization
coordination compounds
titanium
ultrahigh molecular weight polyethylene
mechanical properties
Online Access:https://www.mdpi.com/2073-4360/10/1/2

Internet

https://www.mdpi.com/2073-4360/10/1/2

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