A Synthesis of Six and Seven-membered Heterocyclic Molecules Containing an Adamantyl Fragment and an X-ray Crystal Structure of (E)-N-(adamantan-1-yl)-1-(3-nitrophenyl)methanimine

A Synthesis of Six and Seven-membered Heterocyclic Molecules Containing an Adamantyl Fragment and an X-ray Crystal Structure of (E)-N-(adamantan-1-yl)-1-(3-nitrophenyl)methanimine

       Our work included a synthesis of three new imine derivatives—1,3-thiazinan-4-one, 1,3-oxazinan-6-one and 1,3-oxazepin-4,7-dione—which contained an adamantyl fragment. These were produced via the condensation of the Schiff`s base (E)-N-(adamantan-1-yl)-1-(3-aryl)methanimine with 3-mercaptopro...

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Main Author: Ahmed Shukkur
Format: Article
Language:Arabic
Published: College of Science for Women, University of Baghdad 2020-03-01
Series:Baghdad Science Journal
Subjects:
Adamantan-1-ylamine, 1,3-oxazepin-4,7-dione, 1,3-oxazinan-6-one, 1,3-thiazinan-4-one, X-ray crystallography
Online Access:http://bsj.uobaghdad.edu.iq/index.php/BSJ/article/view/3649
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spelling doaj-e0e36b044aa947e3967f6f0318ad467c2020-11-25T01:30:04ZaraCollege of Science for Women, University of BaghdadBaghdad Science Journal2078-86652411-79862020-03-01171(Suppl.)10.21123/bsj.2020.17.1(Suppl.).0272A Synthesis of Six and Seven-membered Heterocyclic Molecules Containing an Adamantyl Fragment and an X-ray Crystal Structure of (E)-N-(adamantan-1-yl)-1-(3-nitrophenyl)methanimineAhmed Shukkur0University of Anbar        Our work included a synthesis of three new imine derivatives—1,3-thiazinan-4-one, 1,3-oxazinan-6-one and 1,3-oxazepin-4,7-dione—which contained an adamantyl fragment. These were produced via the condensation of the Schiff`s base (E)-N-(adamantan-1-yl)-1-(3-aryl)methanimine with 3-mercaptopropanoic acid; 3-chloropropanoic acid; and maleic, citraconic anhydride, respectively. These new imines were prepared via the condensation of adamantan-1-ylamine and 3-nitro-, 3-bromobenzaldehyde in n-BuOH. We obtained a good yield of products. FTIR, 1H NMR spectroscopy and C.H.N.S analysis were used to diagnostic the products. The molecular structure of (E)-N-(adamantan-1-yl)-1-(3-nitrophenyl)methanimine was confirmed by X-ray crystallography analysis.   http://bsj.uobaghdad.edu.iq/index.php/BSJ/article/view/3649Adamantan-1-ylamine, 1,3-oxazepin-4,7-dione, 1,3-oxazinan-6-one, 1,3-thiazinan-4-one, X-ray crystallography
collection DOAJ
language Arabic
format Article
sources DOAJ
author Ahmed Shukkur
spellingShingle Ahmed Shukkur
A Synthesis of Six and Seven-membered Heterocyclic Molecules Containing an Adamantyl Fragment and an X-ray Crystal Structure of (E)-N-(adamantan-1-yl)-1-(3-nitrophenyl)methanimine
Baghdad Science Journal
Adamantan-1-ylamine, 1,3-oxazepin-4,7-dione, 1,3-oxazinan-6-one, 1,3-thiazinan-4-one, X-ray crystallography
author_facet Ahmed Shukkur
author_sort Ahmed Shukkur
title A Synthesis of Six and Seven-membered Heterocyclic Molecules Containing an Adamantyl Fragment and an X-ray Crystal Structure of (E)-N-(adamantan-1-yl)-1-(3-nitrophenyl)methanimine
title_short A Synthesis of Six and Seven-membered Heterocyclic Molecules Containing an Adamantyl Fragment and an X-ray Crystal Structure of (E)-N-(adamantan-1-yl)-1-(3-nitrophenyl)methanimine
title_full A Synthesis of Six and Seven-membered Heterocyclic Molecules Containing an Adamantyl Fragment and an X-ray Crystal Structure of (E)-N-(adamantan-1-yl)-1-(3-nitrophenyl)methanimine
title_fullStr A Synthesis of Six and Seven-membered Heterocyclic Molecules Containing an Adamantyl Fragment and an X-ray Crystal Structure of (E)-N-(adamantan-1-yl)-1-(3-nitrophenyl)methanimine
title_full_unstemmed A Synthesis of Six and Seven-membered Heterocyclic Molecules Containing an Adamantyl Fragment and an X-ray Crystal Structure of (E)-N-(adamantan-1-yl)-1-(3-nitrophenyl)methanimine
title_sort synthesis of six and seven-membered heterocyclic molecules containing an adamantyl fragment and an x-ray crystal structure of (e)-n-(adamantan-1-yl)-1-(3-nitrophenyl)methanimine
publisher College of Science for Women, University of Baghdad
series Baghdad Science Journal
issn 2078-8665
2411-7986
publishDate 2020-03-01
description        Our work included a synthesis of three new imine derivatives—1,3-thiazinan-4-one, 1,3-oxazinan-6-one and 1,3-oxazepin-4,7-dione—which contained an adamantyl fragment. These were produced via the condensation of the Schiff`s base (E)-N-(adamantan-1-yl)-1-(3-aryl)methanimine with 3-mercaptopropanoic acid; 3-chloropropanoic acid; and maleic, citraconic anhydride, respectively. These new imines were prepared via the condensation of adamantan-1-ylamine and 3-nitro-, 3-bromobenzaldehyde in n-BuOH. We obtained a good yield of products. FTIR, 1H NMR spectroscopy and C.H.N.S analysis were used to diagnostic the products. The molecular structure of (E)-N-(adamantan-1-yl)-1-(3-nitrophenyl)methanimine was confirmed by X-ray crystallography analysis.  
topic Adamantan-1-ylamine, 1,3-oxazepin-4,7-dione, 1,3-oxazinan-6-one, 1,3-thiazinan-4-one, X-ray crystallography
url http://bsj.uobaghdad.edu.iq/index.php/BSJ/article/view/3649
work_keys_str_mv AT ahmedshukkur asynthesisofsixandsevenmemberedheterocyclicmoleculescontaininganadamantylfragmentandanxraycrystalstructureofenadamantan1yl13nitrophenylmethanimine
AT ahmedshukkur synthesisofsixandsevenmemberedheterocyclicmoleculescontaininganadamantylfragmentandanxraycrystalstructureofenadamantan1yl13nitrophenylmethanimine
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