Aqua{4,4′,6,6′-tetrafluoro-2,2′-[(piperazine-1,4-diyl)dimethylene]diphenolato}copper(II)

Aqua{4,4′,6,6′-tetrafluoro-2,2′-[(piperazine-1,4-diyl)dimethylene]diphenolato}copper(II)

In the title compound, [Cu(C18H16F4N2O2)(H2O)], the CuII atom shows a distorted square-pyramidal coordination geometry with the N,N′,O,O′-tetradentate piperazine–diphenolate ligand forming the basal plane. The apical site is occupied by the O atom of a coord...

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Main Authors: Koji Kubono, Yuki Tsuno, Keita Tani, Kunihiko Yokoi
Format: Article
Language:English
Published: International Union of Crystallography 2010-11-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S1600536810040080
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spelling doaj-e097fdf70f0a42e38bf417e71505ecb12020-11-25T01:09:42ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682010-11-016611m1397m139810.1107/S1600536810040080Aqua{4,4′,6,6′-tetrafluoro-2,2′-[(piperazine-1,4-diyl)dimethylene]diphenolato}copper(II)Koji KubonoYuki TsunoKeita TaniKunihiko YokoiIn the title compound, [Cu(C18H16F4N2O2)(H2O)], the CuII atom shows a distorted square-pyramidal coordination geometry with the N,N′,O,O′-tetradentate piperazine–diphenolate ligand forming the basal plane. The apical site is occupied by the O atom of a coordinated water molecule. Neighbouring complexes are associated through intermolecular O—H...O and O—H...F hydrogen bonds between the water molecule and a phenolate O atom or an F atom from an adjacent ligand, respectively, forming a centrosymmetric dimer. Dimers are linked by additional intermolecular C—H...O and C—H...F hydrogen bonds, giving infinite chains propagating along the a axis. http://scripts.iucr.org/cgi-bin/paper?S1600536810040080
collection DOAJ
language English
format Article
sources DOAJ
author Koji Kubono
Yuki Tsuno
Keita Tani
Kunihiko Yokoi
spellingShingle Koji Kubono
Yuki Tsuno
Keita Tani
Kunihiko Yokoi
Aqua{4,4′,6,6′-tetrafluoro-2,2′-[(piperazine-1,4-diyl)dimethylene]diphenolato}copper(II)
Acta Crystallographica Section E
author_facet Koji Kubono
Yuki Tsuno
Keita Tani
Kunihiko Yokoi
author_sort Koji Kubono
title Aqua{4,4′,6,6′-tetrafluoro-2,2′-[(piperazine-1,4-diyl)dimethylene]diphenolato}copper(II)
title_short Aqua{4,4′,6,6′-tetrafluoro-2,2′-[(piperazine-1,4-diyl)dimethylene]diphenolato}copper(II)
title_full Aqua{4,4′,6,6′-tetrafluoro-2,2′-[(piperazine-1,4-diyl)dimethylene]diphenolato}copper(II)
title_fullStr Aqua{4,4′,6,6′-tetrafluoro-2,2′-[(piperazine-1,4-diyl)dimethylene]diphenolato}copper(II)
title_full_unstemmed Aqua{4,4′,6,6′-tetrafluoro-2,2′-[(piperazine-1,4-diyl)dimethylene]diphenolato}copper(II)
title_sort aqua{4,4′,6,6′-tetrafluoro-2,2′-[(piperazine-1,4-diyl)dimethylene]diphenolato}copper(ii)
publisher International Union of Crystallography
series Acta Crystallographica Section E
issn 1600-5368
publishDate 2010-11-01
description In the title compound, [Cu(C18H16F4N2O2)(H2O)], the CuII atom shows a distorted square-pyramidal coordination geometry with the N,N′,O,O′-tetradentate piperazine–diphenolate ligand forming the basal plane. The apical site is occupied by the O atom of a coordinated water molecule. Neighbouring complexes are associated through intermolecular O—H...O and O—H...F hydrogen bonds between the water molecule and a phenolate O atom or an F atom from an adjacent ligand, respectively, forming a centrosymmetric dimer. Dimers are linked by additional intermolecular C—H...O and C—H...F hydrogen bonds, giving infinite chains propagating along the a axis.
url http://scripts.iucr.org/cgi-bin/paper?S1600536810040080
work_keys_str_mv AT kojikubono aqua44amp824266amp8242tetrafluoro22amp8242piperazine14diyldimethylenediphenolatocopperii
AT yukitsuno aqua44amp824266amp8242tetrafluoro22amp8242piperazine14diyldimethylenediphenolatocopperii
AT keitatani aqua44amp824266amp8242tetrafluoro22amp8242piperazine14diyldimethylenediphenolatocopperii
AT kunihikoyokoi aqua44amp824266amp8242tetrafluoro22amp8242piperazine14diyldimethylenediphenolatocopperii
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