Bis{μ-5-(diethylamino)-2-[(2-oxidoethoxy)iminomethyl]phenolato}dicopper(II) acetone solvate

Bis{μ-5-(diethylamino)-2-[(2-oxidoethoxy)iminomethyl]phenolato}dicopper(II) acetone solvate

The title complex, [Cu2(C13H18N2O3)2]·C3H6O, has been synthesized by the reaction of copper(II) acetate monohydrate with 5,5′-bis(diethylamino)-2,2′-[ethylenedioxybis(nitrilomethylidyne)]diphenol, where one of the N—O bonds of the ligand was cleaved during the...

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Main Authors: Zhong-Wu Lv, Xiao-Lu Tang, Xue-Ni He, Xiao Chen, Wen-Kui Dong
Format: Article
Language:English
Published: International Union of Crystallography 2008-09-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S1600536808024707
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spelling doaj-e095ec5428ca4fd8a16b9377709212d12020-11-24T21:52:59ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682008-09-01649m1133m113310.1107/S1600536808024707Bis{μ-5-(diethylamino)-2-[(2-oxidoethoxy)iminomethyl]phenolato}dicopper(II) acetone solvateZhong-Wu LvXiao-Lu TangXue-Ni HeXiao ChenWen-Kui DongThe title complex, [Cu2(C13H18N2O3)2]·C3H6O, has been synthesized by the reaction of copper(II) acetate monohydrate with 5,5′-bis(diethylamino)-2,2′-[ethylenedioxybis(nitrilomethylidyne)]diphenol, where one of the N—O bonds of the ligand was cleaved during the reaction. The complex molecule has a μ-dialkoxo-bridged binuclear structure with both CuII centers exhibiting a square-planar coordination geometry.http://scripts.iucr.org/cgi-bin/paper?S1600536808024707
collection DOAJ
language English
format Article
sources DOAJ
author Zhong-Wu Lv
Xiao-Lu Tang
Xue-Ni He
Xiao Chen
Wen-Kui Dong
spellingShingle Zhong-Wu Lv
Xiao-Lu Tang
Xue-Ni He
Xiao Chen
Wen-Kui Dong
Bis{μ-5-(diethylamino)-2-[(2-oxidoethoxy)iminomethyl]phenolato}dicopper(II) acetone solvate
Acta Crystallographica Section E
author_facet Zhong-Wu Lv
Xiao-Lu Tang
Xue-Ni He
Xiao Chen
Wen-Kui Dong
author_sort Zhong-Wu Lv
title Bis{μ-5-(diethylamino)-2-[(2-oxidoethoxy)iminomethyl]phenolato}dicopper(II) acetone solvate
title_short Bis{μ-5-(diethylamino)-2-[(2-oxidoethoxy)iminomethyl]phenolato}dicopper(II) acetone solvate
title_full Bis{μ-5-(diethylamino)-2-[(2-oxidoethoxy)iminomethyl]phenolato}dicopper(II) acetone solvate
title_fullStr Bis{μ-5-(diethylamino)-2-[(2-oxidoethoxy)iminomethyl]phenolato}dicopper(II) acetone solvate
title_full_unstemmed Bis{μ-5-(diethylamino)-2-[(2-oxidoethoxy)iminomethyl]phenolato}dicopper(II) acetone solvate
title_sort bis{μ-5-(diethylamino)-2-[(2-oxidoethoxy)iminomethyl]phenolato}dicopper(ii) acetone solvate
publisher International Union of Crystallography
series Acta Crystallographica Section E
issn 1600-5368
publishDate 2008-09-01
description The title complex, [Cu2(C13H18N2O3)2]·C3H6O, has been synthesized by the reaction of copper(II) acetate monohydrate with 5,5′-bis(diethylamino)-2,2′-[ethylenedioxybis(nitrilomethylidyne)]diphenol, where one of the N—O bonds of the ligand was cleaved during the reaction. The complex molecule has a μ-dialkoxo-bridged binuclear structure with both CuII centers exhibiting a square-planar coordination geometry.
url http://scripts.iucr.org/cgi-bin/paper?S1600536808024707
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AT xiaolutang bis9565diethylamino22oxidoethoxyiminomethylphenolatodicopperiiacetonesolvate
AT xuenihe bis9565diethylamino22oxidoethoxyiminomethylphenolatodicopperiiacetonesolvate
AT xiaochen bis9565diethylamino22oxidoethoxyiminomethylphenolatodicopperiiacetonesolvate
AT wenkuidong bis9565diethylamino22oxidoethoxyiminomethylphenolatodicopperiiacetonesolvate
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