[N,N′-(1,2-Diphenylethane-1,2-diyl)bis(pyridine-2-carboxamidato)]nickel(II) diethyl ether hemisolvate

[N,N′-(1,2-Diphenylethane-1,2-diyl)bis(pyridine-2-carboxamidato)]nickel(II) diethyl ether hemisolvate

In the title compound, [Ni(C26H20N4O2)]·0.5C4H10O, the central metal ion is coordinated by four atoms of the tetradentate picolinamide ligand, forming a slightly distorted square-planar configuration, with an average Ni—N(pyridine) distance of 1.94 Å and an aver...

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Bibliographic Details
Main Authors: Xiang-Ge Zhou, Mei Li, Dong-Yan Deng, Li Yang
Format: Article
Language:English
Published: International Union of Crystallography 2008-03-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S1600536808002882
Description
Summary:In the title compound, [Ni(C26H20N4O2)]·0.5C4H10O, the central metal ion is coordinated by four atoms of the tetradentate picolinamide ligand, forming a slightly distorted square-planar configuration, with an average Ni—N(pyridine) distance of 1.94 Å and an average Ni—N(amide) distance of 1.83 Å. The asymmetric unit contains one half-molecule of diethyl ether; this solvent molecule is disordered across a twofold rotation axis..
ISSN:1600-5368

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