2-(4-Chlorobenzoyl)-1-(diaminomethylene)hydrazinium chloride monohydrate
In the cation of the title compound, C8H10ClN4O+·Cl−·H2O, the guanidinium group is planar (maximum deviation = 0.0001 Å) and nearly perpendicular to carboxamide group, making a dihedral angle of 87.0 (3)°....
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| Format: | Article |
| Language: | English |
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International Union of Crystallography
2010-05-01
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| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536810014108 |
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doaj-e0690424e8da4a26b4f190173662800d |
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Article |
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doaj-e0690424e8da4a26b4f190173662800d2020-11-25T01:57:02ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682010-05-01665o1152o115310.1107/S16005368100141082-(4-Chlorobenzoyl)-1-(diaminomethylene)hydrazinium chloride monohydrateV. M. ChernyshevA. V. ChernyshevaE. V. TarasovaV. V. IvanovZ. A. StarikovaIn the cation of the title compound, C8H10ClN4O+·Cl−·H2O, the guanidinium group is planar (maximum deviation = 0.0001 Å) and nearly perpendicular to carboxamide group, making a dihedral angle of 87.0 (3)°. The N atoms of the guanidine fragment have a planar trigonal configuration and the N atom of the carboxamide group adopts a pyramidal configuration. In the crystal structure, intermolecular N—H...O, N—H...Cl and O—H...Cl hydrogen bonds link the cations, anions and water molecules into layers parallel to the bc plane. http://scripts.iucr.org/cgi-bin/paper?S1600536810014108 |
| collection |
DOAJ |
| language |
English |
| format |
Article |
| sources |
DOAJ |
| author |
V. M. Chernyshev A. V. Chernysheva E. V. Tarasova V. V. Ivanov Z. A. Starikova |
| spellingShingle |
V. M. Chernyshev A. V. Chernysheva E. V. Tarasova V. V. Ivanov Z. A. Starikova 2-(4-Chlorobenzoyl)-1-(diaminomethylene)hydrazinium chloride monohydrate Acta Crystallographica Section E |
| author_facet |
V. M. Chernyshev A. V. Chernysheva E. V. Tarasova V. V. Ivanov Z. A. Starikova |
| author_sort |
V. M. Chernyshev |
| title |
2-(4-Chlorobenzoyl)-1-(diaminomethylene)hydrazinium chloride monohydrate |
| title_short |
2-(4-Chlorobenzoyl)-1-(diaminomethylene)hydrazinium chloride monohydrate |
| title_full |
2-(4-Chlorobenzoyl)-1-(diaminomethylene)hydrazinium chloride monohydrate |
| title_fullStr |
2-(4-Chlorobenzoyl)-1-(diaminomethylene)hydrazinium chloride monohydrate |
| title_full_unstemmed |
2-(4-Chlorobenzoyl)-1-(diaminomethylene)hydrazinium chloride monohydrate |
| title_sort |
2-(4-chlorobenzoyl)-1-(diaminomethylene)hydrazinium chloride monohydrate |
| publisher |
International Union of Crystallography |
| series |
Acta Crystallographica Section E |
| issn |
1600-5368 |
| publishDate |
2010-05-01 |
| description |
In the cation of the title compound, C8H10ClN4O+·Cl−·H2O, the guanidinium group is planar (maximum deviation = 0.0001 Å) and nearly perpendicular to carboxamide group, making a dihedral angle of 87.0 (3)°. The N atoms of the guanidine fragment have a planar trigonal configuration and the N atom of the carboxamide group adopts a pyramidal configuration. In the crystal structure, intermolecular N—H...O, N—H...Cl and O—H...Cl hydrogen bonds link the cations, anions and water molecules into layers parallel to the bc plane. |
| url |
http://scripts.iucr.org/cgi-bin/paper?S1600536810014108 |
| work_keys_str_mv |
AT vmchernyshev 24chlorobenzoyl1diaminomethylenehydraziniumchloridemonohydrate AT avchernysheva 24chlorobenzoyl1diaminomethylenehydraziniumchloridemonohydrate AT evtarasova 24chlorobenzoyl1diaminomethylenehydraziniumchloridemonohydrate AT vvivanov 24chlorobenzoyl1diaminomethylenehydraziniumchloridemonohydrate AT zastarikova 24chlorobenzoyl1diaminomethylenehydraziniumchloridemonohydrate |
| _version_ |
1724976780894273536 |