Nonlinear detection of secondary isotopic chemical shifts in NMR through spin noise

Nuclear spin noise allows passive monitoring of magnetization using the sole NMR detection circuit. Here, the authors report spectroscopic signatures of low abundance molecules and of weak magnetic field gradients which are nonlinearly amplified by cooled-coil probes and large overlapping signals.

Bibliographic Details
Main Authors: Maria Theresia Pöschko, Victor V. Rodin, Judith Schlagnitweit, Norbert Müller, Hervé Desvaux
Format: Article
Language:English
Published: Nature Publishing Group 2017-01-01
Series:Nature Communications
Online Access:https://doi.org/10.1038/ncomms13914
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spelling doaj-e0169b766872478598c7d1c1a597cff22021-05-11T07:13:29ZengNature Publishing GroupNature Communications2041-17232017-01-01811910.1038/ncomms13914Nonlinear detection of secondary isotopic chemical shifts in NMR through spin noiseMaria Theresia Pöschko0Victor V. Rodin1Judith Schlagnitweit2Norbert Müller3Hervé Desvaux4Institute of Organic Chemistry, Johannes Kepler University LinzInstitute of Organic Chemistry, Johannes Kepler University LinzInstitute of Organic Chemistry, Johannes Kepler University LinzInstitute of Organic Chemistry, Johannes Kepler University LinzNIMBE, CEA, CNRS, Université Paris-Saclay, CEA/SaclayNuclear spin noise allows passive monitoring of magnetization using the sole NMR detection circuit. Here, the authors report spectroscopic signatures of low abundance molecules and of weak magnetic field gradients which are nonlinearly amplified by cooled-coil probes and large overlapping signals.https://doi.org/10.1038/ncomms13914
collection DOAJ
language English
format Article
sources DOAJ
author Maria Theresia Pöschko
Victor V. Rodin
Judith Schlagnitweit
Norbert Müller
Hervé Desvaux
spellingShingle Maria Theresia Pöschko
Victor V. Rodin
Judith Schlagnitweit
Norbert Müller
Hervé Desvaux
Nonlinear detection of secondary isotopic chemical shifts in NMR through spin noise
Nature Communications
author_facet Maria Theresia Pöschko
Victor V. Rodin
Judith Schlagnitweit
Norbert Müller
Hervé Desvaux
author_sort Maria Theresia Pöschko
title Nonlinear detection of secondary isotopic chemical shifts in NMR through spin noise
title_short Nonlinear detection of secondary isotopic chemical shifts in NMR through spin noise
title_full Nonlinear detection of secondary isotopic chemical shifts in NMR through spin noise
title_fullStr Nonlinear detection of secondary isotopic chemical shifts in NMR through spin noise
title_full_unstemmed Nonlinear detection of secondary isotopic chemical shifts in NMR through spin noise
title_sort nonlinear detection of secondary isotopic chemical shifts in nmr through spin noise
publisher Nature Publishing Group
series Nature Communications
issn 2041-1723
publishDate 2017-01-01
description Nuclear spin noise allows passive monitoring of magnetization using the sole NMR detection circuit. Here, the authors report spectroscopic signatures of low abundance molecules and of weak magnetic field gradients which are nonlinearly amplified by cooled-coil probes and large overlapping signals.
url https://doi.org/10.1038/ncomms13914
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AT victorvrodin nonlineardetectionofsecondaryisotopicchemicalshiftsinnmrthroughspinnoise
AT judithschlagnitweit nonlineardetectionofsecondaryisotopicchemicalshiftsinnmrthroughspinnoise
AT norbertmuller nonlineardetectionofsecondaryisotopicchemicalshiftsinnmrthroughspinnoise
AT hervedesvaux nonlineardetectionofsecondaryisotopicchemicalshiftsinnmrthroughspinnoise
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