Nonlinear detection of secondary isotopic chemical shifts in NMR through spin noise
Nuclear spin noise allows passive monitoring of magnetization using the sole NMR detection circuit. Here, the authors report spectroscopic signatures of low abundance molecules and of weak magnetic field gradients which are nonlinearly amplified by cooled-coil probes and large overlapping signals.
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Nature Publishing Group
2017-01-01
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Series: | Nature Communications |
Online Access: | https://doi.org/10.1038/ncomms13914 |
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doaj-e0169b766872478598c7d1c1a597cff22021-05-11T07:13:29ZengNature Publishing GroupNature Communications2041-17232017-01-01811910.1038/ncomms13914Nonlinear detection of secondary isotopic chemical shifts in NMR through spin noiseMaria Theresia Pöschko0Victor V. Rodin1Judith Schlagnitweit2Norbert Müller3Hervé Desvaux4Institute of Organic Chemistry, Johannes Kepler University LinzInstitute of Organic Chemistry, Johannes Kepler University LinzInstitute of Organic Chemistry, Johannes Kepler University LinzInstitute of Organic Chemistry, Johannes Kepler University LinzNIMBE, CEA, CNRS, Université Paris-Saclay, CEA/SaclayNuclear spin noise allows passive monitoring of magnetization using the sole NMR detection circuit. Here, the authors report spectroscopic signatures of low abundance molecules and of weak magnetic field gradients which are nonlinearly amplified by cooled-coil probes and large overlapping signals.https://doi.org/10.1038/ncomms13914 |
collection |
DOAJ |
language |
English |
format |
Article |
sources |
DOAJ |
author |
Maria Theresia Pöschko Victor V. Rodin Judith Schlagnitweit Norbert Müller Hervé Desvaux |
spellingShingle |
Maria Theresia Pöschko Victor V. Rodin Judith Schlagnitweit Norbert Müller Hervé Desvaux Nonlinear detection of secondary isotopic chemical shifts in NMR through spin noise Nature Communications |
author_facet |
Maria Theresia Pöschko Victor V. Rodin Judith Schlagnitweit Norbert Müller Hervé Desvaux |
author_sort |
Maria Theresia Pöschko |
title |
Nonlinear detection of secondary isotopic chemical shifts in NMR through spin noise |
title_short |
Nonlinear detection of secondary isotopic chemical shifts in NMR through spin noise |
title_full |
Nonlinear detection of secondary isotopic chemical shifts in NMR through spin noise |
title_fullStr |
Nonlinear detection of secondary isotopic chemical shifts in NMR through spin noise |
title_full_unstemmed |
Nonlinear detection of secondary isotopic chemical shifts in NMR through spin noise |
title_sort |
nonlinear detection of secondary isotopic chemical shifts in nmr through spin noise |
publisher |
Nature Publishing Group |
series |
Nature Communications |
issn |
2041-1723 |
publishDate |
2017-01-01 |
description |
Nuclear spin noise allows passive monitoring of magnetization using the sole NMR detection circuit. Here, the authors report spectroscopic signatures of low abundance molecules and of weak magnetic field gradients which are nonlinearly amplified by cooled-coil probes and large overlapping signals. |
url |
https://doi.org/10.1038/ncomms13914 |
work_keys_str_mv |
AT mariatheresiaposchko nonlineardetectionofsecondaryisotopicchemicalshiftsinnmrthroughspinnoise AT victorvrodin nonlineardetectionofsecondaryisotopicchemicalshiftsinnmrthroughspinnoise AT judithschlagnitweit nonlineardetectionofsecondaryisotopicchemicalshiftsinnmrthroughspinnoise AT norbertmuller nonlineardetectionofsecondaryisotopicchemicalshiftsinnmrthroughspinnoise AT hervedesvaux nonlineardetectionofsecondaryisotopicchemicalshiftsinnmrthroughspinnoise |
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1721452629884665856 |