INTENSIFICATION OF FLOTATION ISOLATION FINE-EMULSIFIED OF THE TRIBUTYL PHOSPHATE BY MEANS OF ANIONIC COLLECTORS

Positive effect of anion collectors additives — alkylcarboxylates potassium (ACP) on process of tributylphosphate (TBP) flotation isolation from its emulsions is positioned. Optimum ACP is 14 mg/dm3. The most effective collector is potassium myr-istate in which presence the maximum degree of extract...

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Bibliographic Details
Main Authors: V. F. Sazonova, M. A. Kozhemyak
Format: Article
Language:English
Published: Odessa I. I. Mechnikov National University 2016-04-01
Series:Vìsnik Odesʹkogo Nacìonalʹnogo Unìversitetu: Hìmìâ
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Online Access:http://heraldchem.onu.edu.ua/article/view/67174
Description
Summary:Positive effect of anion collectors additives — alkylcarboxylates potassium (ACP) on process of tributylphosphate (TBP) flotation isolation from its emulsions is positioned. Optimum ACP is 14 mg/dm3. The most effective collector is potassium myr-istate in which presence the maximum degree of extraction (amax) desired conditions of experiment is 90 %. Bulk TBP (75-95 % from a ) is extraction for the first 10 min of a flotation. The kinetics of flotation process is described by the equation of the first order. Values of kinetic constants lay within 0,04-0,08 min-1. The time necessary for achievement a is 20-25 min. The fullest TBP is extraction from alkaline medium (pH 9-12).
ISSN:2304-0947
2414-5963