INTENSIFICATION OF FLOTATION ISOLATION FINE-EMULSIFIED OF THE TRIBUTYL PHOSPHATE BY MEANS OF ANIONIC COLLECTORS
Positive effect of anion collectors additives — alkylcarboxylates potassium (ACP) on process of tributylphosphate (TBP) flotation isolation from its emulsions is positioned. Optimum ACP is 14 mg/dm3. The most effective collector is potassium myr-istate in which presence the maximum degree of extract...
Main Authors: | , |
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Format: | Article |
Language: | English |
Published: |
Odessa I. I. Mechnikov National University
2016-04-01
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Series: | Vìsnik Odesʹkogo Nacìonalʹnogo Unìversitetu: Hìmìâ |
Subjects: | |
Online Access: | http://heraldchem.onu.edu.ua/article/view/67174 |
Summary: | Positive effect of anion collectors additives — alkylcarboxylates potassium (ACP) on process of tributylphosphate (TBP) flotation isolation from its emulsions is positioned. Optimum ACP is 14 mg/dm3. The most effective collector is potassium myr-istate in which presence the maximum degree of extraction (amax) desired conditions of experiment is 90 %. Bulk TBP (75-95 % from a ) is extraction for the first 10 min of a flotation. The kinetics of flotation process is described by the equation of the first order. Values of kinetic constants lay within 0,04-0,08 min-1. The time necessary for achievement a is 20-25 min. The fullest TBP is extraction from alkaline medium (pH 9-12). |
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ISSN: | 2304-0947 2414-5963 |