Bis(methyl xanthato)-κS;κ2S:S′-(triphenylphosphane-κP)palladium(II)

Bis(methyl xanthato)-κS;κ2S:S′-(triphenylphosphane-κP)palladium(II)

The title compound, [Pd(C2H3OS2)2(C18H15P)], features a palladium complex with a triphenylphosphane ligand and two xanthate ligands, one of them coordinates in a bidentate and the other in a monodentate fashion, giving rise to a slightly distorted square-planar coordination of the PdII ion. As a res...

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Bibliographic Details
Main Authors: Reyna Reyes-Martínez, Simón Hernández-Ortega, David Morales-Morales
Format: Article
Language:English
Published: International Union of Crystallography 2011-11-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S1600536811040487
Description
Summary:The title compound, [Pd(C2H3OS2)2(C18H15P)], features a palladium complex with a triphenylphosphane ligand and two xanthate ligands, one of them coordinates in a bidentate and the other in a monodentate fashion, giving rise to a slightly distorted square-planar coordination of the PdII ion. As a result of this difference in the coordination modes, the C—S bond lengths are different, viz. 1.687 (2) and 1.692 (2) Å in the bidentate ligand and 1.723 (2) Å in the monodentate ligand, whereas the non-coordinating S atom has a C—S distance of 1.649 (2) Å. The crystal packing is stabilized by C—H...O interactions.
ISSN:1600-5368

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