(Isopropyl xanthato-κ2S,S′)bis(1,10-phenanthroline-κ2N,N′)sodium(I)
The title compound, [Na(C4H7OS2)(C12H8N2)2], is monomeric, with the Na atom chelated by the S atoms of an i-propylxanthate ligand and the N atoms of two 1,10-phenanthroline (phen) ligands. The Na atom is six-coordinate in a distorted trigonal antiprism. A number of π–π st...
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| Format: | Article |
| Language: | English |
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International Union of Crystallography
2008-01-01
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| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536807061910 |
| Summary: | The title compound, [Na(C4H7OS2)(C12H8N2)2], is monomeric, with the Na atom chelated by the S atoms of an i-propylxanthate ligand and the N atoms of two 1,10-phenanthroline (phen) ligands. The Na atom is six-coordinate in a distorted trigonal antiprism. A number of π–π stacking interactions involving the phen rings help to consolidate the crystal packing (centroid–centroid distances lie in the range 3.338–3.443 Å). |
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| ISSN: | 1600-5368 |