Reactions of Chlorine Gas on Benzaldehyde-di-n-alkyl Acetals

Reactions of Chlorine Gas on Benzaldehyde-di-n-alkyl Acetals

Reactions of chlorine gas on six aromatic acetals, the benzaldehyde di-n-alkyl acetals, C6H4-CH(OR)2 where R=ethyl (1a), n-propyl (2a), n-butyl (3a), isobutyl (4a), n-amyl (5a) and isoamyl (6a) were studied. The products were analyzed by IR and 1H NMR spectroscopic techniques and were found to be ri...

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Main Authors: A. Edwin Vasu, K. Joseph Santhanaraj, S. Raja
Format: Article
Language:English
Published: Hindawi Limited 2008-01-01
Series:E-Journal of Chemistry
Online Access:http://dx.doi.org/10.1155/2008/178560
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spelling doaj-df4d7ca0aaf04ff39498d2037bd76fed2020-11-24T21:39:36ZengHindawi LimitedE-Journal of Chemistry0973-49452090-98102008-01-015225125610.1155/2008/178560Reactions of Chlorine Gas on Benzaldehyde-di-n-alkyl AcetalsA. Edwin Vasu0K. Joseph Santhanaraj1S. Raja2Post Graduate and Research Department of Chemistry St. Joseph's College (Autonomous), Tiruchirappalli-620 002, Tamil Nadu, IndiaPost Graduate and Research Department of Chemistry St. Joseph's College (Autonomous), Tiruchirappalli-620 002, Tamil Nadu, IndiaPost Graduate and Research Department of Chemistry St. Joseph's College (Autonomous), Tiruchirappalli-620 002, Tamil Nadu, IndiaReactions of chlorine gas on six aromatic acetals, the benzaldehyde di-n-alkyl acetals, C6H4-CH(OR)2 where R=ethyl (1a), n-propyl (2a), n-butyl (3a), isobutyl (4a), n-amyl (5a) and isoamyl (6a) were studied. The products were analyzed by IR and 1H NMR spectroscopic techniques and were found to be ring chlorinated alkyl benzoates. A plausible mechanism has been proposed based on the experimental observations and the effect of the alkyl groups on the product yield.http://dx.doi.org/10.1155/2008/178560
collection DOAJ
language English
format Article
sources DOAJ
author A. Edwin Vasu
K. Joseph Santhanaraj
S. Raja
spellingShingle A. Edwin Vasu
K. Joseph Santhanaraj
S. Raja
Reactions of Chlorine Gas on Benzaldehyde-di-n-alkyl Acetals
E-Journal of Chemistry
author_facet A. Edwin Vasu
K. Joseph Santhanaraj
S. Raja
author_sort A. Edwin Vasu
title Reactions of Chlorine Gas on Benzaldehyde-di-n-alkyl Acetals
title_short Reactions of Chlorine Gas on Benzaldehyde-di-n-alkyl Acetals
title_full Reactions of Chlorine Gas on Benzaldehyde-di-n-alkyl Acetals
title_fullStr Reactions of Chlorine Gas on Benzaldehyde-di-n-alkyl Acetals
title_full_unstemmed Reactions of Chlorine Gas on Benzaldehyde-di-n-alkyl Acetals
title_sort reactions of chlorine gas on benzaldehyde-di-n-alkyl acetals
publisher Hindawi Limited
series E-Journal of Chemistry
issn 0973-4945
2090-9810
publishDate 2008-01-01
description Reactions of chlorine gas on six aromatic acetals, the benzaldehyde di-n-alkyl acetals, C6H4-CH(OR)2 where R=ethyl (1a), n-propyl (2a), n-butyl (3a), isobutyl (4a), n-amyl (5a) and isoamyl (6a) were studied. The products were analyzed by IR and 1H NMR spectroscopic techniques and were found to be ring chlorinated alkyl benzoates. A plausible mechanism has been proposed based on the experimental observations and the effect of the alkyl groups on the product yield.
url http://dx.doi.org/10.1155/2008/178560
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AT kjosephsanthanaraj reactionsofchlorinegasonbenzaldehydedinalkylacetals
AT sraja reactionsofchlorinegasonbenzaldehydedinalkylacetals
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