[3-Hydroxy-N′-(2-oxidobenzylidene)-2-naphthohydrazidato-κ3O,N,O′]tris(pyridine-κN)nickel(II) pyridine trisolvate

[3-Hydroxy-N′-(2-oxidobenzylidene)-2-naphthohydrazidato-κ3O,N,O′]tris(pyridine-κN)nickel(II) pyridine trisolvate

The asymmetric unit of the crystal structure of the title complex, [Ni(C18H12N2O3)(C5H5N)3]·3C5H5N, contains two independent NiII complex molecules and six uncoordinated pyridine molecules. Each NiII atom is coordinated by two O and four N atoms, from three pyridine and a chelating 3-hydrox...

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Main Authors: Jian-Min Dou, Da-Qi Wang, Da-Cheng Li, Wen-Jun Kang, Shi-Zhu Sun
Format: Article
Language:English
Published: International Union of Crystallography 2008-02-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S1600536808002900
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spelling doaj-df1c193a276c4a2799e938febdab973d2020-11-24T22:08:52ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682008-02-01642m438m43810.1107/S1600536808002900[3-Hydroxy-N′-(2-oxidobenzylidene)-2-naphthohydrazidato-κ3O,N,O′]tris(pyridine-κN)nickel(II) pyridine trisolvateJian-Min DouDa-Qi WangDa-Cheng LiWen-Jun KangShi-Zhu SunThe asymmetric unit of the crystal structure of the title complex, [Ni(C18H12N2O3)(C5H5N)3]·3C5H5N, contains two independent NiII complex molecules and six uncoordinated pyridine molecules. Each NiII atom is coordinated by two O and four N atoms, from three pyridine and a chelating 3-hydroxy-N′-(2-oxidobenzylidene)-2-naphthohydrazide dianionic ligand, with a distorted octahedral geometry. Intramolecular O—H...N hydrogen bonding exists in both complex molecules but no intermolecular hydrogen bonding is observed in the crystal structure.http://scripts.iucr.org/cgi-bin/paper?S1600536808002900
collection DOAJ
language English
format Article
sources DOAJ
author Jian-Min Dou
Da-Qi Wang
Da-Cheng Li
Wen-Jun Kang
Shi-Zhu Sun
spellingShingle Jian-Min Dou
Da-Qi Wang
Da-Cheng Li
Wen-Jun Kang
Shi-Zhu Sun
[3-Hydroxy-N′-(2-oxidobenzylidene)-2-naphthohydrazidato-κ3O,N,O′]tris(pyridine-κN)nickel(II) pyridine trisolvate
Acta Crystallographica Section E
author_facet Jian-Min Dou
Da-Qi Wang
Da-Cheng Li
Wen-Jun Kang
Shi-Zhu Sun
author_sort Jian-Min Dou
title [3-Hydroxy-N′-(2-oxidobenzylidene)-2-naphthohydrazidato-κ3O,N,O′]tris(pyridine-κN)nickel(II) pyridine trisolvate
title_short [3-Hydroxy-N′-(2-oxidobenzylidene)-2-naphthohydrazidato-κ3O,N,O′]tris(pyridine-κN)nickel(II) pyridine trisolvate
title_full [3-Hydroxy-N′-(2-oxidobenzylidene)-2-naphthohydrazidato-κ3O,N,O′]tris(pyridine-κN)nickel(II) pyridine trisolvate
title_fullStr [3-Hydroxy-N′-(2-oxidobenzylidene)-2-naphthohydrazidato-κ3O,N,O′]tris(pyridine-κN)nickel(II) pyridine trisolvate
title_full_unstemmed [3-Hydroxy-N′-(2-oxidobenzylidene)-2-naphthohydrazidato-κ3O,N,O′]tris(pyridine-κN)nickel(II) pyridine trisolvate
title_sort [3-hydroxy-n′-(2-oxidobenzylidene)-2-naphthohydrazidato-κ3o,n,o′]tris(pyridine-κn)nickel(ii) pyridine trisolvate
publisher International Union of Crystallography
series Acta Crystallographica Section E
issn 1600-5368
publishDate 2008-02-01
description The asymmetric unit of the crystal structure of the title complex, [Ni(C18H12N2O3)(C5H5N)3]·3C5H5N, contains two independent NiII complex molecules and six uncoordinated pyridine molecules. Each NiII atom is coordinated by two O and four N atoms, from three pyridine and a chelating 3-hydroxy-N′-(2-oxidobenzylidene)-2-naphthohydrazide dianionic ligand, with a distorted octahedral geometry. Intramolecular O—H...N hydrogen bonding exists in both complex molecules but no intermolecular hydrogen bonding is observed in the crystal structure.
url http://scripts.iucr.org/cgi-bin/paper?S1600536808002900
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AT daqiwang 3hydroxyn82422oxidobenzylidene2naphthohydrazidato9543ono8242trispyridine954nnickeliipyridinetrisolvate
AT dachengli 3hydroxyn82422oxidobenzylidene2naphthohydrazidato9543ono8242trispyridine954nnickeliipyridinetrisolvate
AT wenjunkang 3hydroxyn82422oxidobenzylidene2naphthohydrazidato9543ono8242trispyridine954nnickeliipyridinetrisolvate
AT shizhusun 3hydroxyn82422oxidobenzylidene2naphthohydrazidato9543ono8242trispyridine954nnickeliipyridinetrisolvate
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