Oxidation of aliphatic aldehydes by benzimidazolium fluorochromate in non aqueous medium – A kinetic and mechanistic study

Oxidation of aliphatic aldehydes by benzimidazolium fluorochromate in non aqueous medium – A kinetic and mechanistic study

The oxidation of seven aliphatic aldehydes by benzimidazolium fluorochromate (BIFC) in dimethyl sulphoxide (DMSO) leads to the formation of the corresponding carboxylic acids. The reaction is first order in BIFC. The Michaelis–Menten type kinetics was observed with respect to the aldehyde. The react...

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Bibliographic Details
Main Authors: Basim H. Asghar, S. Sheik Mansoor, A. Mohamed Hussain, V. Saleem Malik, K. Aswin, S.P.N. Sudhan
Format: Article
Language:English
Published: Elsevier 2017-05-01
Series:Arabian Journal of Chemistry
Subjects:
Aliphatic aldehyde
Benzimidazolium fluorochromate
Kinetics
Oxidation
Solvent effect
Online Access:http://www.sciencedirect.com/science/article/pii/S1878535213002438

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http://www.sciencedirect.com/science/article/pii/S1878535213002438

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