Et4N[NO3(SnClPh3)2(SnPh3NO3)]: a trinuclear organostannate complex and related derivatives
Four new di- and triorganonitrato stannate complexes and related derivatives have been synthesized and characterized by infrared and Mössbauer spectroscopy. The structure of Et4N[NO3(SnClPh3)2(SnPh3NO3)] (1) has been determined by single-crystal X-ray diffraction analysis. In the trinuclear organost...
| Main Authors: | , , , |
|---|---|
| Format: | Article |
| Language: | English |
| Published: |
De Gruyter
2013-07-01
|
| Series: | Main Group Metal Chemistry |
| Subjects: | |
| Online Access: | https://doi.org/10.1515/mgmc-2013-0009 |
| Summary: | Four new di- and triorganonitrato stannate complexes and related derivatives have been synthesized and characterized by infrared and Mössbauer spectroscopy. The structure of Et4N[NO3(SnClPh3)2(SnPh3NO3)] (1) has been determined by single-crystal X-ray diffraction analysis. In the trinuclear organostannate complex, each SnIV atom is five-coordinated and adopts a trigonal-bipyramidal trans-OXSnC3 (X=O or Cl) geometry. The overall coordination environment of the SnIV atoms is trans-octahedral for 2 and 3 or cis-trigonal-bipyramidal for 4. In the related derivatives, the NO3- anions behave as monodentate ligands. |
|---|---|
| ISSN: | 0792-1241 2191-0219 |