2,15-Dioxa-7,18,19,20,23-pentaazaheptacyclo[21.6.1.117,20.01,8.03,7.09,14.024,29]hentriaconta-9,11,13,17(31),18,24,26,28-octaen-30-one

2,15-Dioxa-7,18,19,20,23-pentaazaheptacyclo[21.6.1.117,20.01,8.03,7.09,14.024,29]hentriaconta-9,11,13,17(31),18,24,26,28-octaen-30-one

In the title compound, C24H23N5O3, the oxindole ring system is nearly planar, with a dihedral angle between the two fused rings of 3.3 (1)°. In the fused pyrrolo–oxazole ring system, the oxazole and pyrrolidine rings adopt envelope conformations with the spiro C atom and...

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Main Authors: Govindarajulu Rangabashyam Subhashree, Santhanagopalan Purushothaman, Raghavachary Raghunathan, Devadasan Velmurugan, Dasararaju Gayathri
Format: Article
Language:English
Published: International Union of Crystallography 2013-11-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S1600536813027396
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spelling doaj-de59e18876ac4ad09f045d813b516c722020-11-25T01:33:27ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682013-11-016911o1637o163710.1107/S16005368130273962,15-Dioxa-7,18,19,20,23-pentaazaheptacyclo[21.6.1.117,20.01,8.03,7.09,14.024,29]hentriaconta-9,11,13,17(31),18,24,26,28-octaen-30-oneGovindarajulu Rangabashyam SubhashreeSanthanagopalan PurushothamanRaghavachary RaghunathanDevadasan VelmuruganDasararaju GayathriIn the title compound, C24H23N5O3, the oxindole ring system is nearly planar, with a dihedral angle between the two fused rings of 3.3 (1)°. In the fused pyrrolo–oxazole ring system, the oxazole and pyrrolidine rings adopt envelope conformations with the spiro C atom and one of the methylene C atoms, respectively, as the flap atoms. In the crystal, molecules are linked into a helical chain along the b axis via C—H...O interactions generating R21(7) and R22(8) ring motifs.http://scripts.iucr.org/cgi-bin/paper?S1600536813027396
collection DOAJ
language English
format Article
sources DOAJ
author Govindarajulu Rangabashyam Subhashree
Santhanagopalan Purushothaman
Raghavachary Raghunathan
Devadasan Velmurugan
Dasararaju Gayathri
spellingShingle Govindarajulu Rangabashyam Subhashree
Santhanagopalan Purushothaman
Raghavachary Raghunathan
Devadasan Velmurugan
Dasararaju Gayathri
2,15-Dioxa-7,18,19,20,23-pentaazaheptacyclo[21.6.1.117,20.01,8.03,7.09,14.024,29]hentriaconta-9,11,13,17(31),18,24,26,28-octaen-30-one
Acta Crystallographica Section E
author_facet Govindarajulu Rangabashyam Subhashree
Santhanagopalan Purushothaman
Raghavachary Raghunathan
Devadasan Velmurugan
Dasararaju Gayathri
author_sort Govindarajulu Rangabashyam Subhashree
title 2,15-Dioxa-7,18,19,20,23-pentaazaheptacyclo[21.6.1.117,20.01,8.03,7.09,14.024,29]hentriaconta-9,11,13,17(31),18,24,26,28-octaen-30-one
title_short 2,15-Dioxa-7,18,19,20,23-pentaazaheptacyclo[21.6.1.117,20.01,8.03,7.09,14.024,29]hentriaconta-9,11,13,17(31),18,24,26,28-octaen-30-one
title_full 2,15-Dioxa-7,18,19,20,23-pentaazaheptacyclo[21.6.1.117,20.01,8.03,7.09,14.024,29]hentriaconta-9,11,13,17(31),18,24,26,28-octaen-30-one
title_fullStr 2,15-Dioxa-7,18,19,20,23-pentaazaheptacyclo[21.6.1.117,20.01,8.03,7.09,14.024,29]hentriaconta-9,11,13,17(31),18,24,26,28-octaen-30-one
title_full_unstemmed 2,15-Dioxa-7,18,19,20,23-pentaazaheptacyclo[21.6.1.117,20.01,8.03,7.09,14.024,29]hentriaconta-9,11,13,17(31),18,24,26,28-octaen-30-one
title_sort 2,15-dioxa-7,18,19,20,23-pentaazaheptacyclo[21.6.1.117,20.01,8.03,7.09,14.024,29]hentriaconta-9,11,13,17(31),18,24,26,28-octaen-30-one
publisher International Union of Crystallography
series Acta Crystallographica Section E
issn 1600-5368
publishDate 2013-11-01
description In the title compound, C24H23N5O3, the oxindole ring system is nearly planar, with a dihedral angle between the two fused rings of 3.3 (1)°. In the fused pyrrolo–oxazole ring system, the oxazole and pyrrolidine rings adopt envelope conformations with the spiro C atom and one of the methylene C atoms, respectively, as the flap atoms. In the crystal, molecules are linked into a helical chain along the b axis via C—H...O interactions generating R21(7) and R22(8) ring motifs.
url http://scripts.iucr.org/cgi-bin/paper?S1600536813027396
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