Syntheses, Characterization and Study of the Use of Cobalt (II) Schiff–Base Complexes as Catalysts for the Oxidation of Styrene by Molecular Oxygen

Syntheses, Characterization and Study of the Use of Cobalt (II) Schiff–Base Complexes as Catalysts for the Oxidation of Styrene by Molecular Oxygen

Schiff-Base complexes of bis-5-phenylazosalicylaldehyde ethylenediimine and bis-5-phenylazosalicylaldehyde-O-phenylenediimine ligands with Co(II) (I and II) have been synthesized and characterized by their IR spectra and elemental analyses. These complexes catalyze the oxidation of styrene in the pr...

Full description

Bibliographic Details
Main Authors: Zolfaghar Rezvani, Kamellia Nejati, Ali Akbar Khandar
Format: Article
Language:English
Published: MDPI AG 2005-01-01
Series:Molecules
Subjects:
Cobalt
Schiff base complexes
Salicylidene
Styrene
Oxidation
Online Access:http://www.mdpi.com/1420-3049/10/1/302/
id doaj-de0fb8f0bc814563b77d0149de608eb8
record_format Article
spelling doaj-de0fb8f0bc814563b77d0149de608eb82020-11-24T22:09:52ZengMDPI AGMolecules1420-30492005-01-0110130231110.3390/10010302Syntheses, Characterization and Study of the Use of Cobalt (II) Schiff–Base Complexes as Catalysts for the Oxidation of Styrene by Molecular OxygenZolfaghar RezvaniKamellia NejatiAli Akbar KhandarSchiff-Base complexes of bis-5-phenylazosalicylaldehyde ethylenediimine and bis-5-phenylazosalicylaldehyde-O-phenylenediimine ligands with Co(II) (I and II) have been synthesized and characterized by their IR spectra and elemental analyses. These complexes catalyze the oxidation of styrene in the presence of dioxygen and excess pyridine. The effect of the reaction conditions on the oxidation of styrene was studied by varying solvent, nature and amount of the catalyst and substrate. The catalytic behavior of the studied complexes was shown to be dependent on the conditions applied. In all reactions, acetophenone and 1- phenylethanol were the only observed products.http://www.mdpi.com/1420-3049/10/1/302/CobaltSchiff base complexesSalicylideneStyreneOxidation
collection DOAJ
language English
format Article
sources DOAJ
author Zolfaghar Rezvani
Kamellia Nejati
Ali Akbar Khandar
spellingShingle Zolfaghar Rezvani
Kamellia Nejati
Ali Akbar Khandar
Syntheses, Characterization and Study of the Use of Cobalt (II) Schiff–Base Complexes as Catalysts for the Oxidation of Styrene by Molecular Oxygen
Molecules
Cobalt
Schiff base complexes
Salicylidene
Styrene
Oxidation
author_facet Zolfaghar Rezvani
Kamellia Nejati
Ali Akbar Khandar
author_sort Zolfaghar Rezvani
title Syntheses, Characterization and Study of the Use of Cobalt (II) Schiff–Base Complexes as Catalysts for the Oxidation of Styrene by Molecular Oxygen
title_short Syntheses, Characterization and Study of the Use of Cobalt (II) Schiff–Base Complexes as Catalysts for the Oxidation of Styrene by Molecular Oxygen
title_full Syntheses, Characterization and Study of the Use of Cobalt (II) Schiff–Base Complexes as Catalysts for the Oxidation of Styrene by Molecular Oxygen
title_fullStr Syntheses, Characterization and Study of the Use of Cobalt (II) Schiff–Base Complexes as Catalysts for the Oxidation of Styrene by Molecular Oxygen
title_full_unstemmed Syntheses, Characterization and Study of the Use of Cobalt (II) Schiff–Base Complexes as Catalysts for the Oxidation of Styrene by Molecular Oxygen
title_sort syntheses, characterization and study of the use of cobalt (ii) schiffã¢â€â“base complexes as catalysts for the oxidation of styrene by molecular oxygen
publisher MDPI AG
series Molecules
issn 1420-3049
publishDate 2005-01-01
description Schiff-Base complexes of bis-5-phenylazosalicylaldehyde ethylenediimine and bis-5-phenylazosalicylaldehyde-O-phenylenediimine ligands with Co(II) (I and II) have been synthesized and characterized by their IR spectra and elemental analyses. These complexes catalyze the oxidation of styrene in the presence of dioxygen and excess pyridine. The effect of the reaction conditions on the oxidation of styrene was studied by varying solvent, nature and amount of the catalyst and substrate. The catalytic behavior of the studied complexes was shown to be dependent on the conditions applied. In all reactions, acetophenone and 1- phenylethanol were the only observed products.
topic Cobalt
Schiff base complexes
Salicylidene
Styrene
Oxidation
url http://www.mdpi.com/1420-3049/10/1/302/
work_keys_str_mv AT zolfagharrezvani synthesescharacterizationandstudyoftheuseofcobaltiischiffaaabasecomplexesascatalystsfortheoxidationofstyrenebymolecularoxygen
AT kamellianejati synthesescharacterizationandstudyoftheuseofcobaltiischiffaaabasecomplexesascatalystsfortheoxidationofstyrenebymolecularoxygen
AT aliakbarkhandar synthesescharacterizationandstudyoftheuseofcobaltiischiffaaabasecomplexesascatalystsfortheoxidationofstyrenebymolecularoxygen
_version_ 1725810319847063552

Similar Items