Skeletal reorganization divergence of N-sulfonyl ynamides

Skeletal reorganizations are intriguing processes in chemical synthesis due to their mechanism, atom-economy and synthetic versatility. Herein, the authors describe a divergent skeletal reorganization of N-sulfonyl ynamides to thiete sulfones and propargyl sulfonamides.

Bibliographic Details
Main Authors: Linwei Zeng, Yuxin Lin, Jiaming Li, Hironao Sajiki, Hujun Xie, Sunliang Cui
Format: Article
Language:English
Published: Nature Publishing Group 2020-11-01
Series:Nature Communications
Online Access:https://doi.org/10.1038/s41467-020-19467-5
Description
Summary:Skeletal reorganizations are intriguing processes in chemical synthesis due to their mechanism, atom-economy and synthetic versatility. Herein, the authors describe a divergent skeletal reorganization of N-sulfonyl ynamides to thiete sulfones and propargyl sulfonamides.
ISSN:2041-1723