Comparison between a Water-Based and a Solvent-Based Impregnation Method towards Dispersed CuO/SBA-15 Catalysts: Texture, Structure and Catalytic Performance in Automotive Exhaust Gas Abatement

• Main Authors: Qi Xin, Antonella Glisenti, Constantine Philippopoulos, Evangelos Poulakis, Myrjam Mertens, Jeff L. Nyalosaso, Vera Meynen, Pegie Cool
• Format: Article
• Language: English
• Published: MDPI AG 2016-10-01
• Series: Catalysts
• Subjects: copper; ammonia based impregnation; molecular designed dispersion; three-way catalyst
• Online Access: http://www.mdpi.com/2073-4344/6/10/164

Supported copper oxide nanoparticles are a potential candidate for replacing the rare and expensive precious metals within the automotive three-way catalyst. However, a well-designed dispersion method is necessary to allow a stable high loading of active material, compensating its lower intrinsic activity and stability. In this work, a CuO-loaded SBA-15 catalyst has been manufactured by two methods. The ammonia-driven deposition precipitation (ADP) and the molecular designed dispersion (MDD) methods are both considered as efficient deposition methods to provide well-dispersed copper oxide-based catalysts. Their morphology, copper dispersion and the chemical state of copper were characterized and compared. Due to the differences in the synthesis approach, a difference in the obtained copper oxide phases has been observed, leading to a distinct behavior in the catalytic performance. The structure-activity correlation of both catalysts has also been revealed for automotive exhaust gas abatement. Results demonstrate that various copper species can be formed depending on the precursor–support interaction, affecting selectivity and conversion during the catalytic reaction.