1,3,7,9-Tetrakis[2,6-bis(1-methylethyl)phenyl]-2,2,8,8-tetraphenyl-5,10-dithia-1,3,7,9-tetraaza-2,8-disila-4,6-digermadispiro[3.1.3.1]decane acetonitrile monosolvate

1,3,7,9-Tetrakis[2,6-bis(1-methylethyl)phenyl]-2,2,8,8-tetraphenyl-5,10-dithia-1,3,7,9-tetraaza-2,8-disila-4,6-digermadispiro[3.1.3.1]decane acetonitrile monosolvate

In the compound, [η2(N,N)-Ph2Si(NDipp)2Ge(μ-S)]2·CH3CN (Dipp = 2,6-iPr2C6H3), C72H88Ge2N4S2Si2·CH2CN, the dimeric germanethione complex lies about an inversion centre with the two GeIV atoms bridged by two sulfide ligands forming the central Ge2S2 ring. Each GeIV atom is also coordinated by two N at...

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Main Authors: Wenzhen Guo, Fengle Ma, Wenjun Zheng
Format: Article
Language:English
Published: International Union of Crystallography 2016-02-01
Series:IUCrData
Subjects:
germanium(IV)
sulfide
bis(amido)silane
germanethione dimer
crystal structure
Online Access:http://scripts.iucr.org/cgi-bin/paper?S2414314616002996
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record_format Article
spelling doaj-dd43577defd444a0b3fe54a97404b9552020-11-24T21:42:13ZengInternational Union of CrystallographyIUCrData2414-31462016-02-0112x16029910.1107/S2414314616002996sj40061,3,7,9-Tetrakis[2,6-bis(1-methylethyl)phenyl]-2,2,8,8-tetraphenyl-5,10-dithia-1,3,7,9-tetraaza-2,8-disila-4,6-digermadispiro[3.1.3.1]decane acetonitrile monosolvateWenzhen Guo0Fengle Ma1Wenjun Zheng2Institute of Organic Chemistry and College of Chemical and Materials Science, Shanxi Normal University, Gongyuan Street 1, Linfen, Shanxi Province 041004, People's Republic of ChinaInstitute of Organic Chemistry and College of Chemical and Materials Science, Shanxi Normal University, Gongyuan Street 1, Linfen, Shanxi Province 041004, People's Republic of ChinaInstitute of Organic Chemistry and College of Chemical and Materials Science, Shanxi Normal University, Gongyuan Street 1, Linfen, Shanxi Province 041004, People's Republic of ChinaIn the compound, [η2(N,N)-Ph2Si(NDipp)2Ge(μ-S)]2·CH3CN (Dipp = 2,6-iPr2C6H3), C72H88Ge2N4S2Si2·CH2CN, the dimeric germanethione complex lies about an inversion centre with the two GeIV atoms bridged by two sulfide ligands forming the central Ge2S2 ring. Each GeIV atom is also coordinated by two N atoms from the bulky bis(amido)silane ligands in a slightly distorted tetrahedral coordination geometry. An acetonitrile solvent molecule, disordered about an inversion centre, is also present.http://scripts.iucr.org/cgi-bin/paper?S2414314616002996germanium(IV)sulfidebis(amido)silanegermanethione dimercrystal structure
collection DOAJ
language English
format Article
sources DOAJ
author Wenzhen Guo
Fengle Ma
Wenjun Zheng
spellingShingle Wenzhen Guo
Fengle Ma
Wenjun Zheng
1,3,7,9-Tetrakis[2,6-bis(1-methylethyl)phenyl]-2,2,8,8-tetraphenyl-5,10-dithia-1,3,7,9-tetraaza-2,8-disila-4,6-digermadispiro[3.1.3.1]decane acetonitrile monosolvate
IUCrData
germanium(IV)
sulfide
bis(amido)silane
germanethione dimer
crystal structure
author_facet Wenzhen Guo
Fengle Ma
Wenjun Zheng
author_sort Wenzhen Guo
title 1,3,7,9-Tetrakis[2,6-bis(1-methylethyl)phenyl]-2,2,8,8-tetraphenyl-5,10-dithia-1,3,7,9-tetraaza-2,8-disila-4,6-digermadispiro[3.1.3.1]decane acetonitrile monosolvate
title_short 1,3,7,9-Tetrakis[2,6-bis(1-methylethyl)phenyl]-2,2,8,8-tetraphenyl-5,10-dithia-1,3,7,9-tetraaza-2,8-disila-4,6-digermadispiro[3.1.3.1]decane acetonitrile monosolvate
title_full 1,3,7,9-Tetrakis[2,6-bis(1-methylethyl)phenyl]-2,2,8,8-tetraphenyl-5,10-dithia-1,3,7,9-tetraaza-2,8-disila-4,6-digermadispiro[3.1.3.1]decane acetonitrile monosolvate
title_fullStr 1,3,7,9-Tetrakis[2,6-bis(1-methylethyl)phenyl]-2,2,8,8-tetraphenyl-5,10-dithia-1,3,7,9-tetraaza-2,8-disila-4,6-digermadispiro[3.1.3.1]decane acetonitrile monosolvate
title_full_unstemmed 1,3,7,9-Tetrakis[2,6-bis(1-methylethyl)phenyl]-2,2,8,8-tetraphenyl-5,10-dithia-1,3,7,9-tetraaza-2,8-disila-4,6-digermadispiro[3.1.3.1]decane acetonitrile monosolvate
title_sort 1,3,7,9-tetrakis[2,6-bis(1-methylethyl)phenyl]-2,2,8,8-tetraphenyl-5,10-dithia-1,3,7,9-tetraaza-2,8-disila-4,6-digermadispiro[3.1.3.1]decane acetonitrile monosolvate
publisher International Union of Crystallography
series IUCrData
issn 2414-3146
publishDate 2016-02-01
description In the compound, [η2(N,N)-Ph2Si(NDipp)2Ge(μ-S)]2·CH3CN (Dipp = 2,6-iPr2C6H3), C72H88Ge2N4S2Si2·CH2CN, the dimeric germanethione complex lies about an inversion centre with the two GeIV atoms bridged by two sulfide ligands forming the central Ge2S2 ring. Each GeIV atom is also coordinated by two N atoms from the bulky bis(amido)silane ligands in a slightly distorted tetrahedral coordination geometry. An acetonitrile solvent molecule, disordered about an inversion centre, is also present.
topic germanium(IV)
sulfide
bis(amido)silane
germanethione dimer
crystal structure
url http://scripts.iucr.org/cgi-bin/paper?S2414314616002996
work_keys_str_mv AT wenzhenguo 1379tetrakis26bis1methylethylphenyl2288tetraphenyl510dithia1379tetraaza28disila46digermadispiro3131decaneacetonitrilemonosolvate
AT fenglema 1379tetrakis26bis1methylethylphenyl2288tetraphenyl510dithia1379tetraaza28disila46digermadispiro3131decaneacetonitrilemonosolvate
AT wenjunzheng 1379tetrakis26bis1methylethylphenyl2288tetraphenyl510dithia1379tetraaza28disila46digermadispiro3131decaneacetonitrilemonosolvate
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