1,3,7,9-Tetrakis[2,6-bis(1-methylethyl)phenyl]-2,2,8,8-tetraphenyl-5,10-dithia-1,3,7,9-tetraaza-2,8-disila-4,6-digermadispiro[3.1.3.1]decane acetonitrile monosolvate

1,3,7,9-Tetrakis[2,6-bis(1-methylethyl)phenyl]-2,2,8,8-tetraphenyl-5,10-dithia-1,3,7,9-tetraaza-2,8-disila-4,6-digermadispiro[3.1.3.1]decane acetonitrile monosolvate

In the compound, [η2(N,N)-Ph2Si(NDipp)2Ge(μ-S)]2·CH3CN (Dipp = 2,6-iPr2C6H3), C72H88Ge2N4S2Si2·CH2CN, the dimeric germanethione complex lies about an inversion centre with the two GeIV atoms bridged by two sulfide ligands forming the central Ge2S2 ring. Each GeIV atom is also coordinated by two N at...

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Bibliographic Details
Main Authors: Wenzhen Guo, Fengle Ma, Wenjun Zheng
Format: Article
Language:English
Published: International Union of Crystallography 2016-02-01
Series:IUCrData
Subjects:
germanium(IV)
sulfide
bis(amido)silane
germanethione dimer
crystal structure
Online Access:http://scripts.iucr.org/cgi-bin/paper?S2414314616002996
Description
Summary:In the compound, [η2(N,N)-Ph2Si(NDipp)2Ge(μ-S)]2·CH3CN (Dipp = 2,6-iPr2C6H3), C72H88Ge2N4S2Si2·CH2CN, the dimeric germanethione complex lies about an inversion centre with the two GeIV atoms bridged by two sulfide ligands forming the central Ge2S2 ring. Each GeIV atom is also coordinated by two N atoms from the bulky bis(amido)silane ligands in a slightly distorted tetrahedral coordination geometry. An acetonitrile solvent molecule, disordered about an inversion centre, is also present.
ISSN:2414-3146

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