Spatial Distribution and Environmental Significance of Phosphorus Fractions in River Sediments and Its Influencing Factor from Hongze and Tiaoxi Watersheds, Eastern China

• Main Authors: Ja Bawk Marip, Xuyin Yuan, Hai Zhu, Isaac Kwesi Nooni, Solomon O.Y. Amankwah, Nana Agyemang Prempeh, Eyram Norgbey, Taitiya Kenneth Yuguda, Zaw Myo Khaing
• Format: Article
• Language: English
• Published: MDPI AG 2020-08-01
• Series: International Journal of Environmental Research and Public Health
• Subjects: phosphorus fractions; river sediments; influencing factor; sequential extraction; tiaoxi watershed; hongze watershed
• Online Access: https://www.mdpi.com/1660-4601/17/16/5787

This study explored the spatial distribution of phosphorus fractions in river sediments and analyzed the relationship between different phosphorus fractions and their environmental influence on the sediments within different watersheds in Eastern China. River sediments from two inflow watersheds (Hongze and Tiaoxi) to Hongze and Taihu Lake in Eastern China were analyzed by the sequential extraction procedure. Five fractions of sedimentary phosphorus, including freely sorbed phosphorus (NH₄Cl-P), redox-sensitive phosphorus (BD-P), bound phosphorus metal oxide (NaOH-P), bound phosphorus calcium (HCl-P), and residual phosphorus (Res-P) were all analyzed. The orders of rankings for the P fractions of the rivers Anhe and Suihe were HCl-P > NaOH-P > BD-P > NH₄Cl-P and HCl-P > BD-P > NaOH-P > NH₄Cl-P, respectively. For the rank order of the Hongze watershed, HCl-P was higher while the NH₄Cl-P contents were significantly lower. The rank order for the Dongtiaoxi River was NaOH-P > HCl-P > BD-P > NH₄Cl-P, and that of Xitiaoxi River was NaOH-P > BD-P > HCl-P > NH₄Cl-P. Compared with the phosphorus forms of the Tiaoxi watershed, NaOH-P contents were significantly higher compared to HCl-P, which was significantly higher in the Hongze watershed. In comparison, NH₄Cl-P contents were significantly lower in both. Variations may be attributed to differential discharge of the P form in the watershed due to land-use changes and urban river ambient conditions.