Selective deoxygenative alkylation of alcohols via photocatalytic domino radical fragmentations

Selective deoxygenative alkylation of alcohols via photocatalytic domino radical fragmentations

The generation of alkyl radicals through deoxygenation of abundant alcohols via photoredox catalysis is of interest. In this study, the authors report a one-pot strategy for visible-light-promoted photoredox coupling of alcohols with electron-deficient alkenes, assisted by carbon disulfide and triph...

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Main Authors: Hong-Mei Guo, Xuesong Wu
Format: Article
Language:English
Published: Nature Publishing Group 2021-09-01
Series:Nature Communications
Online Access:https://doi.org/10.1038/s41467-021-25702-4
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spelling doaj-dd2cbfe7dd664b6b9f188e8d4121d35a2021-09-12T11:45:32ZengNature Publishing GroupNature Communications2041-17232021-09-0112111010.1038/s41467-021-25702-4Selective deoxygenative alkylation of alcohols via photocatalytic domino radical fragmentationsHong-Mei Guo0Xuesong Wu1Hubei Key Laboratory of Bioinorganic Chemistry & Materia Medica, School of Chemistry and Chemical Engineering, Huazhong University of Science and TechnologyHubei Key Laboratory of Bioinorganic Chemistry & Materia Medica, School of Chemistry and Chemical Engineering, Huazhong University of Science and TechnologyThe generation of alkyl radicals through deoxygenation of abundant alcohols via photoredox catalysis is of interest. In this study, the authors report a one-pot strategy for visible-light-promoted photoredox coupling of alcohols with electron-deficient alkenes, assisted by carbon disulfide and triphenylphosphine.https://doi.org/10.1038/s41467-021-25702-4
collection DOAJ
language English
format Article
sources DOAJ
author Hong-Mei Guo
Xuesong Wu
spellingShingle Hong-Mei Guo
Xuesong Wu
Selective deoxygenative alkylation of alcohols via photocatalytic domino radical fragmentations
Nature Communications
author_facet Hong-Mei Guo
Xuesong Wu
author_sort Hong-Mei Guo
title Selective deoxygenative alkylation of alcohols via photocatalytic domino radical fragmentations
title_short Selective deoxygenative alkylation of alcohols via photocatalytic domino radical fragmentations
title_full Selective deoxygenative alkylation of alcohols via photocatalytic domino radical fragmentations
title_fullStr Selective deoxygenative alkylation of alcohols via photocatalytic domino radical fragmentations
title_full_unstemmed Selective deoxygenative alkylation of alcohols via photocatalytic domino radical fragmentations
title_sort selective deoxygenative alkylation of alcohols via photocatalytic domino radical fragmentations
publisher Nature Publishing Group
series Nature Communications
issn 2041-1723
publishDate 2021-09-01
description The generation of alkyl radicals through deoxygenation of abundant alcohols via photoredox catalysis is of interest. In this study, the authors report a one-pot strategy for visible-light-promoted photoredox coupling of alcohols with electron-deficient alkenes, assisted by carbon disulfide and triphenylphosphine.
url https://doi.org/10.1038/s41467-021-25702-4
work_keys_str_mv AT hongmeiguo selectivedeoxygenativealkylationofalcoholsviaphotocatalyticdominoradicalfragmentations
AT xuesongwu selectivedeoxygenativealkylationofalcoholsviaphotocatalyticdominoradicalfragmentations
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